695211
2-ジ-tert-ブチルホスフィノｰ2′-メチルビフェニル
solid
別名:
t-ブチルMePhos, tBuMePhos
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この商品について
実験式（ヒル表記法）:
C21H29P
CAS番号:
分子量:
312.43
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
MDL number:
製品名
2-ジ-tert-ブチルホスフィノｰ2′-メチルビフェニル, solid, 95%
Quality Level
product line
Buchwald Ligand
assay
95%
form
solid
reaction suitability
reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Reductions
mp
90-95 °C
functional group
phosphine
SMILES string
Cc1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C
InChI
1S/C21H29P/c1-16-12-8-9-13-17(16)18-14-10-11-15-19(18)22(20(2,3)4)21(5,6)7/h8-15H,1-7H3
InChI key
UJONYAVMBYXBJQ-UHFFFAOYSA-N
Application
Legal Information
米国特許番号第6,307,087号および第6,395,916号に従って使用してください。
保管分類
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
資料
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
関連コンテンツ
Buchwald Portfolio: Palladacycles and Ligands
Phosphine Ligand Application Guide
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses