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この商品について
実験式(ヒル表記法):
C26H24NP
CAS番号:
分子量:
381.45
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22
MDL number:
製品名
PhDave-Phos, 97%
Quality Level
assay
97%
form
powder
reaction suitability
reaction type: Cross Couplings, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-C Bond Formation
mp
122-126 °C
functional group
phosphine
SMILES string
CN(C)c1ccccc1-c2ccccc2P(c3ccccc3)c4ccccc4
InChI
1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3
InChI key
JGFXUYLYPITYGR-UHFFFAOYSA-N
Application
Legal Information
米国特許番号第6,307,087号および第6,395,916号に従って使用してください。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
保管分類
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
資料
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
関連コンテンツ
Buchwald Portfolio: Palladacycles and Ligands
Phosphine Ligand Application Guide
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses
