710857
塩化鉄(III) 溶液
0.2 M in 2-methyltetrahydrofuran, solution
別名:
塩化第二鉄 溶液
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この商品について
化学式:
FeCl3
CAS番号:
分子量:
162.20
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
製品名
塩化鉄(III) 溶液, 0.2 M in 2-methyltetrahydrofuran
SMILES string
Cl[Fe](Cl)Cl
InChI
1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI key
RBTARNINKXHZNM-UHFFFAOYSA-K
form
solution
reaction suitability
core: iron
reagent type: catalyst
greener alternative product characteristics
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
concentration
0.2 M in 2-methyltetrahydrofuran
refractive index
n20/D 1.414
density
0.868 g/mL at 25 °C
greener alternative category
, Aligned
Quality Level
関連するカテゴリー
Application
Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used:
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
- As a mild oxidant for phenolic coupling reaction.
- In dimerizing aryllithiumsand ketone enolates.
- As a mild Lewis acid catalyst to catalyzes ene reactions.
- In Nazarov cyclizations, Michael additions, and acetonation reactions.
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl3 is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2
supp_hazards
保管分類
3 - Flammable liquids
wgk
WGK 2
flash_point_f
14.0 °F - closed cup
flash_point_c
-10.0 °C - closed cup
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
第4類:引火性液体 + 第一石油類 + 危険等級II + 非水溶性液体
fsl
名称等を表示すべき危険物及び有害物
ishl_indicated
名称等を通知すべき危険物及び有害物
ishl_notified
710857-VAR: + 710857-50ML:4548173924168 + 710857-BULK:
jan
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
William H DePas et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(7), 2629-2634 (2013-01-30)
Bacterial biofilm formation is a complex developmental process involving cellular differentiation and the formation of intricate 3D structures. Here we demonstrate that exposure to ferric chloride triggers rugose biofilm formation by the uropathogenic Escherichia coli strain UTI89 and by enteric
D C Florian Wieland et al.
Colloids and surfaces. B, Biointerfaces, 109, 74-81 (2013-04-27)
The early stages of the formation of inorganic aggregates, composed of iron compounds at the solution-air interface, were investigated in situ. The properties of the solution-air interface were changed by using different Langmuir layers. In order to get insight into
Dattatraya H Dethe et al.
Organic letters, 15(3), 429-431 (2013-01-16)
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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