749613
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium tetrafluoroborate
97%
別名:
DMTMM, MMTM
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この商品について
実験式（ヒル表記法）:
C10H17BF4N4O3
分子量:
328.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C10H17N4O3.BF4/c1-14(4-6-17-7-5-14)8-11-9(15-2)13-10(12-8)16-3;2-1(3,4)5/h4-7H2,1-3H3;/q+1;-1
SMILES string
F[B-](F)(F)F.COc1nc(OC)nc(n1)[N+]2(C)CCOCC2
InChI key
LCRXDNPNQMIQFZ-UHFFFAOYSA-N
assay
97%
form
solid
mp
202-207 °C
functional group
ether
Quality Level
Application
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium tetrafluoroborate (DMTMM BF4) can be used as a coupling reagent alternative to DMTMM Cl in peptide synthesis because of its stability. It is also used in the synthesis of:
- Esters and peptides in both solution and solid-phase.
- γ-aminobutyric acid (GABA)-containing cyclic heptapeptide, unguisin A.
- The cyclization of linear tetrapeptides.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
保管分類
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
Deleterious substance
pdsc
Class I Designated Chemical Substances
prtr
749613-VAR: + 749613-5G:4548173320434 + 749613-1G:4548173320427 + 749613-BULK:
jan
George Lo Huang et al.
Nanomaterials (Basel, Switzerland), 9(5) (2019-05-12)
Indoleamine 2,3-dioxygenase (IDO) is an immunomodulating enzyme that is overexpressed in many cancers with poor prognosis. IDO suppresses T cell immunity by catabolizing tryptophan into kynurenine (KYN), which induces apoptosis in T effector cells and enhances T regulatory cells, providing
Xiaoqin Zhang et al.
Carbohydrate polymers, 247, 116749-116749 (2020-08-25)
To enhance the drug delivery efficiency of hyaluronic acid (HA), we designed and prepared glycodendron and pyropheophorbide-a (Ppa)-functionalized HA (HA-Ppa-Dendron) as a nanosystem for cancer photodynamic therapy. Linear Ppa-modified HA (HA-Ppa) was also prepared as a control. Cellular uptake of
An improved process for the synthesis of DMTMM-based coupling reagents
Raw SA
Tetrahedron Letters, 50(8), 946-948 (2009)
Total synthesis of unguisin A
Hunter L and Chung JH
The Journal of Organic Chemistry, 76(13), 5502-5505 (2011)
Maria Laura Alfieri et al.
Antioxidants (Basel, Switzerland), 9(3) (2020-03-22)
The ability of gelatin-based hydrogels of incorporating and releasing under controlled conditions 5,6-dihydroxyindole-2-carboxylic acid (DHICA), a melanin-related metabolite endowed with marked antioxidant properties was investigated. The methyl ester of DHICA, MeDHICA, was also tested in view of its higher stability
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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