764183
APhos Pd G3
97%, solid
別名:
APhos-Pd-G3, [4-（ジ-tert-ブチルホスフィノ）-N,N-ジメチルアニリン-2-（2′-アミノビフェニル）]パラジウム（II）メタンスルホン酸, パラジウムG3-（4-（N,N-ジメチルアミノ）フェニル）ジ-tert-ブチルホスフィン
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この商品について
製品名
APhos Pd G3, 97%
Quality Level
product line
Buchwald precatalyst Generation 3
assay
97%
form
solid
feature
generation 3
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
greener alternative product score
old score: 5
new score: 3
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sustainability
Greener Alternative Product
mp
192-201 °C (decomposition)
functional group
phosphine
greener alternative category
SMILES string
NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.CN(C)C3=CC=C(C=C3)P(C(C)(C)C)C(C)(C)C
InChI
1S/C16H28NP.C12H10N.CH4O3S.Pd/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12H,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key
SNUBBUQVCDWEAV-UHFFFAOYSA-M
General description
Application
保管分類
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
資料
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
Tools aid in kit setup for organic chemistry techniques, ensuring ease and success.
All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form.
関連コンテンツ
Explore reliable, premium grade catalysis materials for your pharma or industrial project. Specialty chemicals and formulations are available in bulk quantities and volumes from a few grams to multi-metric tons with complete documentation to simplify your leap from development to commercialization.
The Buchwald group has developed a series of highly active and versatile palladium precatalysts and biarylphosphine ligands used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The ligands are electron-rich, and highly tunable to provide catalyst systems with a diverse scope, high stability and reactivity. Furthermore, the new series of precatalysts are air-, moisture and thermally-stable and display good solubility in common organic solvents. The use of precatalysts ensures the efficient generation of the active catalytic species and allows one to accurately adjust the ligand:palladium ratio. The ligands, precatalysts and methodology developed in the Buchwald group are user friendly and have rendered previously difficult cross couplings reactions, much easier to achieve.