908568
[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6
≥95%, powder or crystals
別名:
[5,5′-Bis(trifluoromethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate
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この商品について
実験式（ヒル表記法）:
C36H16F22IrN4P
CAS番号:
分子量:
1145.69
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
製品名
[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: Photocatalysis, reagent type: catalyst
mp
>300 °C
photocatalyst activation
460 nm
SMILES string
[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)C(F)(F)F)c3c(c(cc(c3)F)F)c4ncc(cc4)C(F)(F)F.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F
InChI
1S/C12H6F6N2.2C12H5F5N.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-7(2,3,4,5)6;/h1-6H;2*1-2,4-6H;;/q;;;-1;+1
InChI key
QEXYETWHTSSWGM-UHFFFAOYSA-N
Application
[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
保管分類
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable