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Merck

940321

硫化リチウム

greener alternative

99.995% trace metals basis (basis), low sodium, battery grade

別名:

Dilithium monosulfide, Dilithium sulfide

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この商品について

実験式(ヒル表記法):
Li2S
CAS番号:
分子量:
45.95
UNSPSC Code:
12352300
MDL number:
NACRES:
NA.21
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Quality Level

grade

battery grade

description

application(s): battery manufacturing

assay

99.995% trace metals basis (basis)

form

powder

mol wt

45.95

composition

Li2S

reaction suitability

core: lithium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

particle size

100 mesh

bp

1,372 °C ((lit.))

mp

900-975 °C

solubility

soluble (reacts with water)

density

1.66 g/mL at 25 °C (lit.)

cation traces

Na: <35 ppm

greener alternative category

storage temp.

2-8°C

SMILES string

[Li]S[Li]

InChI

1S/2Li.S

InChI key

ZWDBUTFCWLVLCQ-UHFFFAOYSA-N

General description

Lithium sulfide (Li₂S) is a high-purity, inorganic compound that appears as a white to yellowish crystalline powder. It has a molecular weight of 45.95 g/mol and a density of 1.66 g/cm³. Lithium sulfide is known for its strong nucleophilic properties and its ability to react readily with water to produce lithium hydroxide and hydrogen sulfide gas. It is also soluble in certain organic solvents, such as pyridine and dimethyl sulfoxide. Lithium sulfide crystallizes in an antifluorite structure and melts in the temperature range of 900-975°C. Our high-purity material (99.995% trace metals) is specifically formulated for low sodium content, with less than 35 ppm of sodium metal. Additionally, the material is passed through a 100 mesh sieve, ensuring that most particles are less than 150 microns in size.




Lithium Sulfide is a key material in advanced lithium-sulfur batteries, offering high energy density and low cost. Its use supports greener technologies by enabling lighter, longer-lasting batteries with reduced reliance on scarce metals, promoting sustainable and environmentally friendly energy storage solutions. Click here for more information.

Application

High-purity lithium sulfide is primarily used as a precursor in the synthesis of other lithium compounds. In chemical manufacturing, it acts as a precursor for lithium hydride, lithium borohydride, lithium amide, lithium thioacetate, lithium tetrafluoroborate, and others. In the battery industry, our battery grade lithium sulfide is used as a precursor to synthesize sulfide-based solid electrolytes like Li₃PS₄ ([https://www.sigmaaldrich.com/US/en/product/aldrich/916374]), Li₆PS₅Cl ([https://www.sigmaaldrich.com/US/en/product/aldrich/916137]), and Li₁₀SnP₂S₁₂ ([https://www.sigmaaldrich.com/US/en/product/aldrich/915114]). Lithium sulfide also serves as a cathode material in lithium-sulfur batteries, offering a theoretical capacity of up to 1166 mAh/g, nearly four times that of lithium cobalt oxide. This makes it an attractive candidate for next-generation battery technologies. Additionally, lithium sulfide is valuable in the semiconductor industry for the production of thin-film transistors (TFTs) and other electronic devices, particularly lithium sulfide-phosphorus oxide (Li₂S-P₂O₅) TFTs.

Features and Benefits

  • Higher Purity (99.995%): Ensures minimal trace metal contamination, making it ideal for applications requiring high-purity materials.
  • Low Sodium Content: Specifically formulated for low sodium content (<35 ppm) to meet the stringent requirements of sensitive applications.
  • Controlled Particle Size: Passed through a 100 mesh sieve, ensuring most particles are less than 150 microns, which is crucial for consistent performance in various applications.


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pictograms

Skull and crossbonesCorrosion

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

保管分類

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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