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Merck

437573

N,N-ジメチルホルムアミド

ACS reagent, ≥99.8%

別名:

DMF, NSC 5356

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この商品について

化学式:
HCON(CH3)2
CAS番号:
分子量:
73.09
EC Number:
200-679-5
UNSPSC Code:
12352111
PubChem Substance ID:
Beilstein/REAXYS Number:
605365
MDL number:
Grade:
ACS reagent
Assay:
≥99.8%
Technique(s):
electrophoresis: suitable
Bp:
153 °C (lit.)
Vapor pressure:
2.7 mmHg ( 20 °C)
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製品名

N,N-ジメチルホルムアミド, ACS reagent, ≥99.8%

InChI key

ZMXDDKWLCZADIW-UHFFFAOYSA-N

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

SMILES string

[H]C(=O)N(C)C

grade

ACS reagent

vapor density

2.5 (vs air)

vapor pressure

2.7 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

autoignition temp.

833 °F

expl. lim.

15.2 %

technique(s)

electrophoresis: suitable

impurities

≤0.0005 meq/g Titr. acid
≤0.003 meq/g Titr. base
≤0.15% water

evapn. residue

≤0.005%

color

APHA: ≤15

refractive index

n20/D 1.430 (lit.)

pH

6.7

bp

153 °C (lit.)

mp

−61 °C (lit.)

solubility

water: miscible

density

0.944 g/mL (lit.)

Quality Level

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Application

多くの疎水性有機化合物に用いられる溶媒です。
N,N-Dimethylformamide (DMF) may be used in the following processes:
  • As a solvent synthesis of gold nanoparticles.
  • As a solvent in capillary electrophoresis.
  • Regioselective synthesis of N,N-dimethylaminopyridzines by reacting with choropyridazines.
  • Synthesis of urea-N,N-dimethylformamide, a 3:1 solvate with urea.

General description

N,N-Dimethylformamide (DMF) is a polar organic solvent with a wide range of industrial applications. It is a precursor for numerous reactions such as formylation, aminocarbonylation, amination, amidation and cyanation. Along with phosphorus oxychloride, it forms Vilsmeier reagent used in the formylation of reactive aromatic and heteroaromatic substrates. Dielectric relaxation experiments on DMF have been conducted between 238.15K and 338.15K. The thermophysical properties of the molecular interactions between DMF and the ionic liquids, ammonium salts and imidazolium salts have been studied. The characteristics of solute-solvent interactions between ammonium nitrate and DMF have been investigated.
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

保管分類

3 - Flammable liquids

wgk

WGK 2

flash_point_f

135.5 °F - closed cup

flash_point_c

57.5 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Preparation of gold nanoparticles in formamide and N,N-dimethylformamide in the presence of poly (amidoamine) dendrimers with surface methyl ester groups.
Esumi K, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 189(1), 155-161 (2001)
Reaction of chloropyridazines with N,N -dimethylformamide.
Lee WS, et al.
Journal of Heterocyclic Chemistry, 37(6), 1591-1591 (2000)
N,N-dimethylformamide as a reaction medium for metal nanoparticle synthesis.
Pastoriza-Santos I and Liz-Marzan LM.
Advances in Functional Materials, 19(5), 679-688 (2009)
Urea-N,N-dimethylformamide (3/1).
Fernandes P, et al.
Acta Crystallographica Section E, Structure Reports Online, 63(12), 4861-4861 (2007)
Capillary electrophoresis in N,N-dimethylformamide.
Porras SP and Kenndler E.
Electrophoresis, 26(17), 3279-3291 (2005)

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