77450
2-ブロモアセトフェノン
derivatization grade (GC derivatization), LiChropur™, ≥99.0%
別名:
ω-ブロモアセトフェノン, フェナシルブロミド
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この商品について
化学式:
C6H5COCH2Br
CAS番号:
分子量:
199.04
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-724-9
Beilstein/REAXYS Number:
606474
MDL number:
製品名
2-ブロモアセトフェノン, derivatization grade (GC derivatization), LiChropur™, ≥99.0%
InChI key
LIGACIXOYTUXAW-UHFFFAOYSA-N
InChI
1S/C8H7BrO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2
SMILES string
BrCC(=O)c1ccccc1
grade
derivatization grade (GC derivatization)
assay
≥99.0% (GC)
≥99.0%
form
crystals
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Acylations
technique(s)
gas chromatography (GC): suitable
bp
135 °C/18 mmHg (lit.)
mp
48-51 °C (lit.)
49-50 °C
storage temp.
2-8°C
Quality Level
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関連するカテゴリー
Application
酸から結晶性エステルを調製する際に使用します。
General description
2-Bromoacetophenone is a commonly used derivatization agent for fatty acid detection in biological samples.
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
保管分類
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
High-performance liquid chromatography of fatty acids in biological samples.
Lima ES and Abdalla DSP
Analytica Chimica Acta, 465(1-2), 81-91 (2002)
P A Wender et al.
Organic letters, 1(13), 2117-2120 (2000-06-03)
[formula: see text] 4'-Bromoacetophenone derivatives which upon excitation can generate monophenyl radicals capable of hydrogen atom abstraction were investigated as photoinducible DNA cleaving agents. Pyrrolecarboxamide-conjugated 4'-bromoacetophenones were synthesized, and their DNA cleaving activities and sequence selectivities were determined.
Gulnur Arabaci et al.
Bioorganic & medicinal chemistry letters, 12(21), 3047-3050 (2002-10-10)
A series of alpha-haloacetophenone derivatives was tested for inhibition of protein tyrosine phosphatases SHP-1 and PTP1B. The results show that the bromides are much more potent than the corresponding chlorides, whereas the phenyl ring is remarkably tolerant to modifications. Derivatization
T Endoh et al.
Carcinogenesis, 17(3), 467-475 (1996-03-01)
Effects of inhibitors of arachidonic acid (AA) metabolism on the development of fatty liver, cirrhosis, glutathione-S-transferase placental form (GST-P)-positive nodules and the generation of 8-hydroxydeoxyguanosine (8-OHdG) and thiobarbituric acid-reactive substances (TBARS), caused by a choline-deficient, L-amino acid-defined (CDAA) diet, were
Mostafa A Hussein et al.
Acta pharmaceutica (Zagreb, Croatia), 59(4), 365-382 (2009-11-19)
5-Acyl-8-hydroxyquinoline-2-(3'-substituted-4'-aryl-2,3-dihydrothiazol-2'-ylidene)hydrazones, 5a-e to 10a-c, were prepared by the reaction of appropriate 5-acyl-8-hydroxyquinoline-4-substituted thiosemicarbazones 3a-e and phenacyl bromides 4a-e. Structures of the new compounds were verified on the basis of spectral and elemental analyses. Twenty-eight new compounds were tested for their
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