936669
DPPF
solid
別名:
1,1′-フェロセンジイル-ビス(ジフェニルホスフィン), 1,1′-フェロセンビス(ジフェニルホスフィン), dppf
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この商品について
実験式（ヒル表記法）:
C34H28FeP2
CAS番号:
分子量:
554.38
UNSPSC Code:
12352100
MDL number:
NACRES:
NA.21
製品名
DPPF,
InChI
1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;
SMILES string
[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI key
HPXNTHKXCYMIJL-UHFFFAOYSA-N
Quality Level
product line
ChemBeads
form
solid
composition
loading, 4-6 wt. %
reaction suitability
reagent type: ligand
greener alternative product characteristics
Waste Prevention
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
181-182 °C (dec.) (lit.)
greener alternative category
関連するカテゴリー
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Greener Chemistry. ChemBeads are advanced solid-coated beads for high-throughput experimentation in various chemical applications. They enable precise dispensing of solid reagents, allowing researchers to conduct reactions with minimal material use, thus supporting waste prevention and catalysis principles while ensuring accuracy and reproducibility. This technology enhances efficiency and streamlines experimental processes in chemistry. Click here for more information.
The ChemBeads product of the 1,1′-Bis(diphenylphosphino)ferrocene (DPPF) ligand. DPPF is a bis-phosphine ligand bearing two diphenylphosphine moieties with a ferrocene backbone. Loaded on glass beads for use in high-throughput expermentation (HTE).
Application
- DPPF has been used as a ligand in:
- The ruthenium catalyzed N-alkylation of amines and sulfonamides using borrowing hydrogen methodology.[1] (19191700)
- The cooperative Cu/Pd catalyzed borylallenylation of trifluoromethyl-1,3-enynes to generate conjugated bisallenes.[2] (36321461)
- The cooperative Cu/Pd catlyzed borocarbonylation of ethylene.[3] (36226440)
- The gold catalyzed synthesis of 2-phosphoryl indolin-3-ones.[4] (35815915)
- The iron-catalyzed vinylzincation of terminal alkynes.[5] (34935372) ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
- For general uses, product is also available in powdered form (177261)
保管分類
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
936669-1G: + 936669-BULK: + 936669-VAR:
jan
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