938750
GPhos ChemBeads
solid
別名:
(3-(tert-Butoxy)-2′,6′-diisopropyl-6-methoxy-[1,1′-biphenyl]-2-yl)dicyclohexylphosphane ChemBeads
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この商品について
実験式（ヒル表記法）:
C35H53O2P
CAS番号:
分子量:
536.77
UNSPSC Code:
12352100
MDL number:
NACRES:
NA.21
製品名
GPhos ChemBeads,
Quality Segment
product line
ChemBeads
form
solid
composition
loading of catalyst, 4-6 wt. %
reaction suitability
reaction type: Cross Couplings, reagent type: catalyst, reagent type: ligand
greener alternative product characteristics
Waste Prevention
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
230-233 °C
functional group
phosphine
greener alternative category
SMILES string
CC(C(C=CC=C1C(C)C)=C1C2=C(OC)C=CC(OC(C)(C)C)=C2P(C3CCCCC3)C4CCCCC4)C
InChI
1S/C35H53O2P/c1-24(2)28-20-15-21-29(25(3)4)32(28)33-30(36-8)22-23-31(37-35(5,6)7)34(33)38(26-16-11-9-12-17-26)27-18-13-10-14-19-27/h15,20-27H,9-14,16-19H2,1-8H3
InChI key
JKLUIDIKASJZCK-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Greener Chemistry. ChemBeads are advanced solid-coated beads for high-throughput experimentation in various chemical applications. They enable precise dispensing of solid reagents, allowing researchers to conduct reactions with minimal material use, thus supporting waste prevention and catalysis principles while ensuring accuracy and reproducibility. This technology enhances efficiency and streamlines experimental processes in chemistry. Click here for more information.
GPhos is a Buchwald-type ligand used in various cross-coupling reactions.
Application
GPhos is a dialkylbiaryl monophosphine ligand developed by the Buchwald group for aryl amination reactions. The GPhos Pd oxidative addition complex (OAC) enables room temperature C-N couplings with complex substrates at higher efficiency than previously developed ligands.
Learn more about Buchwald Phosphine Ligands
For general uses, product is also available in powdered form (918008)
Learn more about Buchwald Phosphine Ligands
For general uses, product is also available in powdered form (918008)
Features and Benefits
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
保管分類
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable