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Merck

938963

Potassium tert-butoxide ChemBeads

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solid

別名:

Potassium tert-butylate, Potassium t-butoxide

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実隓匏ヒル衚蚘法:
KOC4H9
CAS番号:
分子量:
112.21
UNSPSC Code:
12352100
MDL number:
NACRES:
NA.21
Form:
solid
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補品名

Potassium tert-butoxide ChemBeads,

description

Reagent Type-Organic Salt

Quality Segment

product line

ChemBeads

form

solid

composition

wt% loading of base, 14-16 wt. %

reaction suitability

core: potassium

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

greener alternative category

SMILES string

[K+].CC(C)(C)[O-]

InChI

1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1

InChI key

LPNYRYFBWFDTMA-UHFFFAOYSA-N

General description

Potassium tert-butoxide is a strong alkoxide base, it can deprotonate carbon and other Brφnsted acids. It is a relatively poor nucleophile.

Application

Potassium tert-butoxide has been used as a strong base in the enantioselective synthesis of amines by transfer hydrogenation of N-(tertbutylsulfinyl)imines. It can also be used: To synthesize aliphatic and aromatic amides from corresponding esters and amines. As a base in the intramolecular cyclization of aryl ethers, amines, and amides. As a catalyst to prepare styrene derivatives from aryl halides and alkenes by Mizoroki-Heck reaction.
For general uses, product is also available in powdered form (156671)

Features and Benefits

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign and has been enhanced for catalytic efficiency. Click here for more information.


pictograms

FlameCorrosion

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Danger

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 2 - Skin Corr. 1A

supp_hazards

保管分類

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3



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