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Merck

360481

1,4-Dioxane

ACS reagent, ≥99.0%, contains ≤50 ppm BHT as stabilizer

동의어(들):

Diethylene oxide, Dioxane

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
C4H8O2
CAS 번호:
Molecular Weight:
88.11
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-661-8
Beilstein/REAXYS Number:
102551
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Bp:
100-102 °C (lit.)
Vapor pressure:
27 mmHg ( 20 °C), 40 mmHg ( 25 °C)
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grade

ACS reagent

Quality Segment

vapor density

3 (vs air)

vapor pressure

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

assay

≥99.0%

form

liquid

autoignition temp.

356 °F

contains

≤50 ppm BHT as stabilizer

expl. lim.

22 %

dilution

(for analytical testing)

impurities

≤0.0016 meq/g Titr. acid, ≤0.005% Peroxide (as H2O2), ≤0.01% Carbonyl (as HCHO), ≤0.05% water

evapn. residue

≤0.005%

color

APHA: ≤20

refractive index

n20/D 1.422 (lit.)

pH

6.0-8 (20 °C, 500 g/L)

bp

100-102 °C (lit.)

mp

10-12 °C (lit.)

transition temp

freezing point ≥11.0

density

1.034 g/mL at 25 °C (lit.)

SMILES string

C1COCCO1

InChI

1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2

InChI key

RYHBNJHYFVUHQT-UHFFFAOYSA-N

General description

1,4-Dioxane is a heterocyclic organic compound that is commonly used as a solvent in several chemical reactions. It is also used as a stabilizer in chlorinated solvents.
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.

Application

1,4-Dioxane can be used as:      
  • A solvent in the N-methylation of amines by reductive functionalization of CO2 in the presence of NaBH4 as the reducing reagent.      
  • An additive to synthesize 3-hydroxylisoindolin-1-ones via hydroxylhydrative aza-cyclization of 2-alkynylbenzamide.

A mixture of 1,4-dioxane/ethanol/formic acid solvent system can be used in the depolymerization of lignin to synthesize value-added phenolic monomers.


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Danger

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

저장 등급

3 - Flammable liquids

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup



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