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Merck

113018

Crotonic acid

98%

Synonym(s):

trans-2-Butenoic acid

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About This Item

Linear Formula:
CH3CH=CHCOOH
CAS Number:
Molecular Weight:
86.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-533-9
Beilstein/REAXYS Number:
1719943
MDL number:
Assay:
98%
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vapor density

2.97 (vs air)

Quality Level

vapor pressure

0.19 mmHg ( 20 °C)

assay

98%

autoignition temp.

744 °F

expl. lim.

15.1 %, 171 °F, 2.2 %, 135 °F

bp

180-181 °C (lit.)

mp

70-72 °C (lit.)

solubility

H2O: soluble

density

1.027 g/mL at 25 °C (lit.)

functional group

carboxylic acid

SMILES string

[H]\C(C)=C(\[H])C(O)=O

InChI

1S/C4H6O2/c1-2-3-4(5)6/h2-3H,1H3,(H,5,6)/b3-2+

InChI key

LDHQCZJRKDOVOX-NSCUHMNNSA-N

General description

Crotonic acid undergoes esterification with butan-2-ol by following second order reaction kinetics.

Application

Crotonic acid is used in the copolymerization of crotonic acid hydrogel systems by using gamma-rays. The crosslinked copolymeric crotonic acid hydrogels release fertilizers and drugs that help to prevent environmental pollution.

Preparation Note

Crotonic acid dissolves in water at a concentartion of 100 mg/ml to yield a clear, colorless solution.


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

190.4 °F - closed cup

flash_point_c

88 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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S W Fessenden et al.
Journal of dairy science, 102(4), 3023-3035 (2019-02-26)
The objective of this study was to evaluate the effects of a fermentation byproduct on rumen fermentation and microbial yield in high producing lactating dairy cattle. Eight ruminally cannulated multiparous Holstein cows averaging (mean ± standard deviation) 60 ± 10
Susana Melo Gesteira et al.
PloS one, 14(4), e0216047-e0216047 (2019-04-27)
The objective of this study was to evaluate the effect of condensed tannin inclusion (0, 10, 30 or 50 g/kg of dry matter (DM) total) from Acacia mearnsii extract on the fatty acid profile, physicochemical quality and sensorial analysis of
Johannes Waschke et al.
PloS one, 14(4), e0214815-e0214815 (2019-04-03)
Adhesive interactions of soft materials play an important role in nature and technology. Interaction energies can be quantified by determining contact areas of deformable microparticles with the help of reflection interference contrast microscopy (RICM). For high throughput screening of adhesive