Skip to Content
Merck

745480

Zinc isopropylsulfinate

95%

Synonym(s):

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Empirical Formula (Hill Notation):
C6H14O4S2Zn
CAS Number:
1416821-55-0
Molecular Weight:
279.69
NACRES:
NA.22
PubChem Substance ID:
329764984
UNSPSC Code:
12352001
MDL number:
MFCD24386390
Assay:
95%
Form:
solid

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

SMILES string

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI key

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

assay

95%

form

solid

reaction suitability

reaction type: Allylation, reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: diversification reagent

mp

161-166 °C

functional group

sulfinic acid

Quality Level

100

Related Categories

Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Preparation Note

may contain up to 1 mole eq ZnCl2

Other Notes

Frequently Asked Questions are available for this Product.
Previously sold under product number L511161

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCN1076
MKCJ2637
MKCD0333
MKCB0914V
MKBX5822V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Yan-Jie Chunyu et al.
Journal of agricultural and food chemistry, 67(31), 8476-8484 (2019-07-13)
Cicada flowers, which are edible and medicinal mushrooms, are the fruiting bodies of Isaria cicadae, a fungus that is parasitic on the larvae of cicada pupae. We hypothesize that host factors might possess stimulatory activity on metabolite synthesis in Isaria
Lucia K Zaugg et al.
Clinical oral implants research, 29(1), 82-90 (2017-10-19)
The purpose of this study was to analyze the cement excess produced when cementing CAD/CAM-fabricated lithium disilicate (L) or zirconium dioxide (Z) crowns using adhesive cement (A) or resin-modified glass ionomer cement (B). Three different cementation techniques were applied: palatal
Xiaopeng Guo et al.
Environmental science and pollution research international, 23(24), 24758-24767 (2016-09-24)
This paper studies the relationship among carbon emissions, GDP, and logistics by using a panel data model and a combination of statistics and econometrics theory. The model is based on the historical data of 10 typical provinces and cities in
Thapanee Srichumpong et al.
Dental materials journal, 38(3), 378-387 (2019-03-15)
The mica-based glass-ceramics were prepared in the SiO2-Al2O3-MgO-MgF2-SrCO3-CaCO3-CaF2-P2O5 glass system. There were four mica-based glass-ceramics produced in this study according to the pigment added (CeO2 or Pr-ZrSiO4/Fe-ZrSiO4) and crystallization time (5-35 min). Four dental glass-ceramics, which were leucite-based, lithium disilicate-based
Young-Hoo Kim et al.
The Journal of arthroplasty, 31(11), 2520-2524 (2016-10-19)
The results of third-generation of alumina-on-alumina ceramic bearing in a large number of patient cohorts are limited. The purpose of this study was to determine clinical and radiologic outcome, prevalence of osteolysis detected with radiographs and computerized tomographic scan, and
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service