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Merck

203521

Lanthanum(III) chloride heptahydrate

99.999% trace metals basis

Synonym(s):

Lanthanum trichloride heptahydrate, Lanthanum(3+) trichloride heptahydrate

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About This Item

Linear Formula:
LaCl3 · 7H2O
CAS Number:
Molecular Weight:
371.37
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
99.999% trace metals basis
Form:
solid
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Quality Level

InChI

1S/3ClH.La.7H2O/h3*1H;;7*1H2/q;;;+3;;;;;;;/p-3

SMILES string

O.O.O.O.O.O.O.Cl[La](Cl)Cl

InChI key

FDFPDGIMPRFRJP-UHFFFAOYSA-K

assay

99.999% trace metals basis

form

solid

reaction suitability

core: lanthanum, reagent type: catalyst

impurities

≤15.0 ppm Trace Rare Earth Analysis

mp

91 °C (dec.) (lit.)

application(s)

electroplating
material synthesis precursor

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General description

Lanthanum(III)chloride heptahydrate is a mild, inexpensive, and moisture-stable heterogeneouscatalyst widely used in several organic transformations.

Application

Lanthanum(III) chloride heptahydrate can be used as an efficient catalyst for :
  • Solvent-free preparation of substituted alkenes via Knoevenagel condensation.
  • One-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones.
It can be used as a precursor to synthesize La/V co-doped TiO2 nanoparticles through the sol-gel method. La co-doped TiO2 nanopowder show enhanced photocatalytic activity.

Biochem/physiol Actions

Calcium channel blocker

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

flash_point_f

does not flash

flash_point_c

does not flash

ppe

dust mask type N95 (US), Eyeshields, Gloves

Storage Class

13 - Non Combustible Solids


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Anna Citta et al.
Journal of inorganic biochemistry, 117, 18-24 (2012-10-20)
Lanthanum chloride (LaCl(3)) is a good inhibitor of both the cytosolic and mitochondrial thioredoxin reductase with IC(50) values of 1.75 and 7.46 μM, respectively. On the contrary, the related enzyme glutathione reductase is not inhibited by lanthanum ions even at
Adan Schafer Medina et al.
Journal of radioanalytical and nuclear chemistry, 324(3), 1021-1030 (2020-07-01)
Microliter volumes are used in electrochemical detection and preconcentration of radionuclides to reduce the dose received by researchers and equipment. Unfortunately, there is a lack of analysis of radionuclides with coupled electrochemical techniques and microliter volume reactors. The goals of
Yasuhiko Suzuki et al.
Biochemical and biophysical research communications, 410(2), 317-321 (2011-06-15)
Bradykinin (BK), a mediator of pain and inflammation, is involved in bone metabolism. We have previously reported that BK increased the synthesis of interleukin-6 and prostaglandin E(2) via phosphorylation of ERK1/2 in human osteoblasts, SaM-1. In the present study, we
Paola Ciceri et al.
Biochemical and biophysical research communications, 418(4), 770-773 (2012-02-09)
Phosphate (Pi)-binders are commonly used in dialysis patients to control high Pi levels, that associated with vascular calcification (VC). The aim of this study was to investigate the effects of lanthanum chloride (LaCl(3)) on the progression of high Pi-induced VC
Mario Pink et al.
Journal of proteomics, 75(2), 375-383 (2011-08-30)
Posttranslational modification (PTM) of proteins, particularly phosphorylation, is a key element in the regulation of cell functions. In many signal transduction processes, PTM is a pivotal step. Various analytical methods have been proposed for the identification of phosphoproteins; however, most

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