424684
Phenethylmagnesium chloride solution
1.0 M in THF
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About This Item
Linear Formula:
C6H5CH2CH2MgCl
CAS Number:
Molecular Weight:
164.92
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C8H9.ClH.Mg/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
SMILES string
Cl[Mg]CCc1ccccc1
InChI key
AZORNQXQALOFHH-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
bp
65 °C
density
0.954 g/mL at 25 °C
functional group
phenyl
Quality Level
Related Categories
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles
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Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method
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