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Merck

446785

Perfluorotetradecanoic acid

96%

Synonym(s):

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-Heptacosafluorotetradecanoic acid, Perfluoro-n-tetradecanoic acid, Perfluoromyristic acid, Perfluorotetradecanecarboxylic acid

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About This Item

Linear Formula:
CF3(CF2)12CO2H
CAS Number:
376-06-7
Molecular Weight:
714.11
NACRES:
NA.22
PubChem Substance ID:
24868296
UNSPSC Code:
12352100
EC Number:
206-803-4
MDL number:
MFCD00153263
Assay:
96%
Form:
solid

Key Documents

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InChI key

RUDINRUXCKIXAJ-UHFFFAOYSA-N

InChI

1S/C14HF27O2/c15-2(16,1(42)43)3(17,18)4(19,20)5(21,22)6(23,24)7(25,26)8(27,28)9(29,30)10(31,32)11(33,34)12(35,36)13(37,38)14(39,40)41/h(H,42,43)

SMILES string

OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

assay

96%

form

solid

bp

270 °C/740 mmHg (lit.)

mp

130-135 °C (lit.)

functional group

carboxylic acid, fluoro

Quality Level

100

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Application

Perfluorotetradecanoic acid can be used as a reactant:
  • In the metal-free synthesis of organic iodides using N-iodoamides through the Iododecarboxylation method.
  • To synthesize benzimidazole tethered perfluoromacromolecules by reacting with o-phenylene diamine via condensation reaction.
It can also be used as a surfactant in the formation of mixed monolayer films at the air-water interface.

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1

target_organs

Liver

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

376-06-7

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ7577
MKCM4646
MKCL1419
MKCG8533
MKCD6932

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David Sowah-Kuma et al.
Langmuir : the ACS journal of surfaces and colloids, 34(36), 10673-10683 (2018-08-14)
Synchrotron-based X-ray scattering measurements of phase-separated surfactant monolayers at the air-water interface provide molecular-level structural information about the packing and ordering of film components. In this work, grazing incidence X-ray diffraction (GIXD) and X-ray reflectivity (XR) measurements were used to
Effrosyni Zafeiraki et al.
Chemosphere, 94, 169-176 (2013-12-25)
Perfluorinated compounds (PFCs) are used in food packaging materials as coatings/additives for oil and moisture resistance. In the current study, foodstuff-packaging materials collected from the Greek market, made of paper, paperboard or aluminum foil were analyzed for the determination of
Hyoung Kun Park et al.
Langmuir : the ACS journal of surfaces and colloids, 20(12), 4851-4858 (2005-06-30)
The effect of an acidic surfactant, perfluorotetradecanoic acid (PFTDA), on the gelation of octadecyltrimethoxysilane (ODTMS) monolayers at the air/water interface was investigated using a Langmuir film balance, attenuated total reflection (ATR) infrared spectroscopy, and atomic force microscopy (AFM). The gelation
Hessamaddin Younesi Araghi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 129, 339-344 (2014-04-22)
Photoillumination of mixed films comprised of the photopolymerizable fatty acid 10,12 pentacosadiynoic acid and perfluorotetradecanoic acid deposited onto glass substrates gives rise to the formation of oriented polydiacetylene photopolymer fibers. The degree of polymer fiber orientation was investigated using dual-view
Wei Zhao et al.
Journal of environmental sciences (China), 56, 272-280 (2017-06-03)
Perfluoroalkyl substances (PFASs) are a class of fluorine substituted carboxylic acid, sulfonic acid and alcohol, structurally similar to their corresponding parent compounds. Previous study demonstrated the potential endocrine disruption and reproductive toxicity of perfluorooctane sulfonic acid and perfluorooctanoic acid, two
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