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Merck

06547

Methyl formate

analytical standard

Synonym(s):

Formic acid methyl ester

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About This Item

Linear Formula:
HCO2CH3
CAS Number:
107-31-3
Molecular Weight:
60.05
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
329748243
EC Number:
203-481-7
Beilstein/REAXYS Number:
1734623
MDL number:
MFCD00003291

Key Documents

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Product Name

Methyl formate, analytical standard

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

SMILES string

[H]C(=O)OC

grade

analytical standard

vapor density

2.1 (vs air)

assay

≥99.8% (GC)

autoignition temp.

842 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

23 %

refractive index

n20/D 1.343 (lit.)
n20/D 1.344

bp

32-34 °C (lit.)

mp

−100 °C (lit.)

density

0.974 g/mL at 20 °C (lit.)

application(s)

cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care

format

neat

Quality Level

100

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Application

Methyl formate may be used as a reference standard for the determination of methyl formate in
  • blood and urine by headspace in-tube extraction gas chromatography-mass spectrometry (HS-ITEX-GC−MS)
  • Brazilian sugar-cane spirit by high-resolution gas chromatography (HRGC)
  • pharmaceutical excipients using HS-GC-MS operating under scan mode and selected ion monitoring (SIM) mode

General description

Methyl formate is an ester derivative of formic acid.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-2.2 °F - closed cup

flash_point_c

-19 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD6892
BCCC5118
BCBV8418
BCBQ4800V

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Identification and dosage by HRGC of minor alcohols and esters in Brazilian sugar-cane spirit.
Boscolo M, et al.
Journal of the Brazilian Chemical Society, 11(1), 86-90 (2000)
Formic acid
Ullmann's Encyclopedia of Industrial Chemistry (2000)
Simultaneous determination of formic acid and formaldehyde in pharmaceutical excipients using headspace GC/MS.
del Barrio MA, et al.
Journal of Pharmaceutical and Biomedical Analysis, 41(3), 738-743 (2006)
Ilpo Rasanen et al.
Journal of analytical toxicology, 34(3), 113-121 (2010-04-22)
A novel headspace in-tube extraction gas chromatography-mass spectrometry (ITEX-GC-MS) approach was developed for broad-scale analysis of low molecular weight organic compounds in blood and/or urine. One sample was analyzed following in-vial derivatization with dimethyl sulfate for ethylene glycol (EG), glycolic
Søren T Larsen et al.
Archives of toxicology, 86(2), 285-292 (2011-10-05)
Methyl formate (MF) is a volatile solvent with several industrial applications. The acute airway effects of MF were evaluated in a mouse bioassay, allowing the assessment of sensory irritation of the upper airways, airflow limitation of the conducting airways and
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