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Merck

30315-M

Potassium iodide

puriss. p.a., reag. ISO, reag. Ph. Eur., ≥99.0%

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About This Item

Linear Formula:
KI
CAS Number:
Molecular Weight:
166.00
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-659-4
MDL number:
Assay:
≥99.0%, 99.0-100.5% (calc. to the dried substance)
Form:
crystalline
Solubility:
water: complete (ca.1,430 g/l at 25 °C (77 °F))
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InChI

1S/HI.K/h1H;/q;+1/p-1

InChI key

NLKNQRATVPKPDG-UHFFFAOYSA-M

SMILES string

[K+].[I-]

agency

reag. ISO, reag. Ph. Eur.

vapor pressure

1 mmHg ( 745 °C)

grade

puriss. p.a.

assay

≥99.0%, 99.0-100.5% (calc. to the dried substance)

form

crystalline

impurities

Reducing substances, complies, ≤0.0005% heavy metals (as Pb), ≤0.005% thiosulfate (S2O3), ≤0.02% free alkali (as KOH), ≤10 ppm total nitrogen (N)

loss

≤0.2% loss on drying, 105 °C

pH

6-8 (20 °C, 5%)

mp

681 °C (lit.)

Quality Level

solubility

water: complete (ca.1,430 g/l at 25 °C (77 °F))

anion traces

bromide, chloride (as Cl-): ≤100 ppm, iodate (IO3-): ≤2 ppm, phosphate (PO43-): ≤10 ppm, sulfate (SO42-): ≤10 ppm

cation traces

As: ≤0.00001%, Ba: ≤0.002%, Ca: ≤0.001%, Fe: ≤0.0003%, Mg: ≤0.001%, Na: ≤0.03%

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Application

Potassium iodide is used:
  • As a solid base catalyst loaded with alumina for transesterification of soybean oil with methanol.
  • As a iodide source in the solvothermal synthesis of BiOI (bismuth oxyiodide) microspheres using ethylene glycol solvent.
  • In the synthesis of RGO (reduced graphene oxide) from GO (graphite oxide) in presence of HCl–KI mixture.

General description

Potassium iodide (KI) is an inorganic potassium salt. It is used as an iodide ion source for nucleophilic displacement reactions and acts as a mediator during the electrochemical oxidations of aldehydes. In presence of an acid, KI cleaves some ethers. KI reacts with sulfonyl chlorides to produce symmetrical thiosulfonic S-esters. In the presence of oxidizing agents, KI iodinates aromatic compounds and organothallium compounds.

pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

STOT RE 1 Oral

target_organs

Thyroid

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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