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Merck

38912

Dimethyl ether

puriss., ≥99.9% (GC)

Synonym(s):

Methyl ether

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About This Item

Linear Formula:
(CH3)2O
CAS Number:
Molecular Weight:
46.07
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-065-8
Beilstein/REAXYS Number:
1730743
MDL number:
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Product Name

Dimethyl ether, puriss., ≥99.9% (GC)

InChI key

LCGLNKUTAGEVQW-UHFFFAOYSA-N

InChI

1S/C2H6O/c1-3-2/h1-2H3

SMILES string

COC

vapor density

1.62 (vs air)

vapor pressure

>760 mmHg ( 25 °C)

grade

puriss.

assay

≥99.9% (GC)

autoignition temp.

662 °F

expl. lim.

27 %

bp

−24.8 °C (lit.)

mp

−141 °C (lit.)

functional group

ether

Quality Level

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Application

DME can be used as a precursor for the preparation of versatile methylating agents such as dimethyl sulfate and trimethyloxonium tetrafluoroborate.

General description

Dimethyl ether (DME) is the simplest aliphatic ether used as a reactant as well as a solvent in organic synthesis. It is also used as a precursor for the preparation of important useful organic compounds such as dimethyl carbonate, methyl acetate, propylene and chloromethyl ether.

Other Notes

Sales restrictions may apply
Z742161 DIN 1 Regulator OR 99112 outlet Valve

Packaging

Cylinder with net 1.1 kg
DIN 477 nr.1

pictograms

FlameGas cylinder

signalword

Danger

hcodes

Hazard Classifications

Flam. Gas 1A - Press. Gas Liquefied gas

Storage Class

2A - Gases

wgk

WGK 1

flash_point_f

-41.8 °F - closed cup

flash_point_c

-41 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves


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Trimethyloxonium tetrafluoroborate
Curphey, TJ
Organic Syntheses, 50(4), 1019-1023 (1988)
Hideki Kanda et al.
Water environment research : a research publication of the Water Environment Federation, 83(1), 23-25 (2011-02-05)
We proposed a method for the deodorising and dewatering of biosolids. In the proposed method, liquefied dimethyl ether (DME) was used as an extractant for odorous components and water. We developed a bench-scale experiment to almost completely deodorize and dewater
Wu Zhou et al.
Nature chemistry, 1(9), 722-728 (2010-12-03)
Tungstated zirconia is a robust solid acid catalyst for light alkane (C(4)-C(8)) isomerization. Several structural models for catalytically active sites have been proposed, but the topic remains controversial, partly because of the absence of direct structural imaging information on the
Bruce L Yoder et al.
The Journal of chemical physics, 138(4), 044202-044202 (2013-02-08)
We present a new experimental configuration for the study of size-dependent, angle-resolved photoelectron and photoion spectra of weakly bound ultrafine aerosol particles targeted at particle sizes below ~20 nm. It combines single photon ionization by a tunable, table-top vacuum ultraviolet
M Naqvi et al.
Bioresource technology, 101(3), 937-944 (2009-09-22)
There is great interest in developing black liquor gasification technology over recent years for efficient recovery of bio-based residues in chemical pulp mills. Two potential technologies of producing dimethyl ether (DME) and methane (CH(4)) as alternative fuels from black liquor

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