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About This Item
Linear Formula:
KHSO4
CAS Number:
Molecular Weight:
136.17
PubChem Substance ID:
eCl@ss:
38030413
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
231-594-1
MDL number:
Grade:
reagent grade
Form:
powder or crystals
InChI key
CHKVPAROMQMJNQ-UHFFFAOYSA-M
InChI
1S/K.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1
SMILES string
[K+].OS([O-])(=O)=O
grade
reagent grade
form
powder or crystals
concentration
35.0-37.0% H2SO4 (titration)
mp
214 °C (lit.)
acid number
35‑37%(as H2SO4)
density
2.32 g/mL at 25 °C (lit.)
Quality Level
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Application
Potassium bisulfate (Potassium hydrogen sulfate) may be employed as a catalyst in the synthesis of butyl paraben and methyl cinnamate. It may also be used for the gravimetric estimation of beryllium in beryl.
Potassium bisulfate may be used:
- As a catalyst for the preparation of butyl paraben from p-hydroxybenzoic acid and n-butyl alcohol.
- As a promoter for the synthesis of 3,4-dihydropyrimidin-2(1H)-one derivatives via Biginelli reaction in ethylene glycol.
- As an acid catalyst for the synthesis of ethyl tert-butyl ether (ETBE) from ethanol and tert-butyl alcohol via reactive distillation.
- As a dehydrating agent for the synthesis of pyruvic acid from tartaric acid.
General description
Potassium bisulfate is a water soluble inorganic salt mainly used as a preservative, as a flux and also in the manufacture of fertilizers.
Potassium bisulfate is an inorganic potassium salt. On heating it from 300 to 700°C, it transforms to molten form and the reactions occurring in this transition have been investigated by Raman spectra. Its electrical conductance values have been evaluated (T = 0-700C, Pressure = upto 4000bars).
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Synthesis of Methyl Cinnamate using Potassium Bisulfate as Catalyst [J].
4Danmei LSL.
Guangzhou Chemical Industry/ Guangzhou Huagong, 2, 005-005 (2003)
Synthesis of Butyl Paraben Catalyzed by Potassium Bisulfate [J].
Jianying CDZHH.
Food and Fermentation Industries, 11, 022-022 (2006)
PYRUVIC ACID
Organic Syntheses, 4, 63-63 (1925)
Determination of beryllium and titanium with benzoylacetanilide.
Sarkar AK and Das J.
Analytical Chemistry, 39(13), 1608-1612 (1967)
Electrical Conductances of Aqueous Solutions at High Temperatures and Pressures. III. The Conductances of Potassium Bisulfate Solutions from 0 to 700? and at Pressures to 4000 Bars1.
Quist AS and Marshall WL.
The Journal of Physical Chemistry, 70(11), 3714-3725 (1966)
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