T24007
Tetramethylsilane
NMR grade, ACS reagent, ≥99.9%
Synonym(s):
TMS
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About This Item
Linear Formula:
Si(CH3)4
CAS Number:
Molecular Weight:
88.22
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-899-1
Beilstein/REAXYS Number:
1696908
MDL number:
Assay:
≥99.9%
Grade:
ACS reagent
Technique(s):
NMR: suitable
Bp:
26-28 °C (lit.)
Vapor pressure:
11.66 psi ( 20 °C)
InChI
1S/C4H12Si/c1-5(2,3)4/h1-4H3
SMILES string
C[Si](C)(C)C
InChI key
CZDYPVPMEAXLPK-UHFFFAOYSA-N
grade
ACS reagent
vapor pressure
11.66 psi ( 20 °C)
assay
≥99.9%
form
liquid
autoignition temp.
842 °F
expl. lim.
0.34-6.3 %
technique(s)
NMR: suitable
evapn. residue
≤0.05%
refractive index
n20/D 1.358 (lit.)
bp
26-28 °C (lit.)
mp
−99 °C (lit.)
density
0.648 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
Tetramethylsilane can be used as:
- A precursor to synthesize α-SiC by chemical vapor deposition.
- A reactant to synthesize 1,3,5,7-tetramethyladamantane from adamantane in the presence of aluminum chloride and dichloromethane.
- A solvent for the hydroaminomethylation of 1-octene with morpholine.
- A methylating reagent for the conversion of germanium tetrachloride to tetramethylgermanium, trimethylgermanium chloride, dimethylgermanium dichloride or methylgermanium trichloride.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 1
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-16.6 °F - closed cup
flash_point_c
-27 °C - closed cup
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A novel approach to selecting thermomorphic multicomponent solvent systems (TMS) for hydroaminomethylation reactions
Behr A, et al.
Chemical Engineering and Processing, 69, 15-23 (2013)
Synthesis of alpha-SiC from tetramethylsilane by chemical vapor deposition at high temperature
Jeong S, et al.
Applied Physics Express, 7, 025501-025501 (2014)
Tetramethylsilane in synthesis: selective mono-and polymethylations of germanium tetrachloride
Bordeau M, et al.
Organometallics, 1087-1089, 4-4 (1985)
James C Salamanca et al.
Scientific reports, 8(1), 7559-7559 (2018-05-17)
E-cigarette aerosol emission studies typically focus on benchmarking toxicant levels versus those of cigarettes. However, such studies do not fully account for the distinct chemical makeup of e-liquids and their unique properties. These approaches often conclude that there are fewer
Ramesh C Sharma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 65(3-4), 787-791 (2006-03-15)
The decomposition of trimethylsilane and tetramethylsilane has been investigated for the first time, using hot wire (catalytic) at various temperatures. Trimethylsilane is catalytic-dissociated in these species SiH(2), CH(3)SiH, CH(3), CH(2)Si. Time of flight mass spectroscopy signal of these species are
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