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676578

Bis(tri-tert-butylphosphine)palladium(0)

solid

greener alternative

Greener Alternative

Synonym(s):

Pd(t-Bu3P)2

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About This Item

Empirical Formula (Hill Notation):
C24H54P2Pd
CAS Number:
53199-31-8
Molecular Weight:
511.05
UNSPSC Code:
12161600
PubChem Substance ID:
24884857
NACRES:
NA.22
MDL number:
MFCD03094580
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Product Name

Bis(tri-tert-butylphosphine)palladium(0),

form

solid

Quality Segment

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

sustainability

Sustainability features

mp

258-272 °C

greener alternative category

storage temp.

−20°C

SMILES string

[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C

InChI

1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;

InChI key

MXQOYLRVSVOCQT-UHFFFAOYSA-N

General description

This product aligns with one or more of the 12 Principles of Green Chemistry Find details here.

Application

Catalyst for greener Heck reaction in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
  • Catalyst for Suzuki coupling on a multisubstituted sp3-carbon (eq. 1)
  • Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
  • Catalyst for Negishi coupling reaction (eq. 3)
  • Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
  • Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
  • Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)

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Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

No data available

Flash Point (°C)

No data available

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