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About This Item
Empirical Formula (Hill Notation):
C2BF2NaO4
CAS Number:
Molecular Weight:
159.82
MDL number:
UNSPSC Code:
12352104
NACRES:
NA.21
grade
battery grade
Quality Level
description
Application: Battery manufacturing
assay
≥99%
form
powder
greener alternative product characteristics
Design for Energy Efficiency
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sustainability
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impurities
≤0.2% H2O
anion traces
chloride (Cl-): ≤50 ppm, sulfate (SO42-): ≤20 ppm
cation traces
Ca: ≤20 ppm, K: ≤20 ppm, Mg: ≤20 ppm
application(s)
battery manufacturing
greener alternative category
SMILES string
O=C1C(O[B-](F)(F)([Na+])O1)=O
General description
Sodium difluoro(oxalato)borate, also referred to as NaDFOB, is a high-purity and low-water content white crystalline powder that has become increasingly popular in the field of battery technology. NaDFOB is the sodium equivalent of lithium difluoro(oxalato)borate and is soluble in polar organic solvents (>1.0 M in carbonates), making it ideal for use in battery electrolytes. It exhibits excellent electrochemical stability, surpassing NaClO4, with NaDFOB-based carbonate electrolytes showing electrochemical stability windows above 5.5V vs Na+/Na. Our NaDFOB is manufactured to the highest standards to ensure its purity, enabling it to be used effectively in a wide range of battery applications.
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Application
Sodium-difluoro(oxalato)borate, anhydrous and battery-grade with a purity of ≥99%, is a versatile electrolyte additive for sodium-ion batteries (SIBs). NaDFOB demonstrates superior compatibility with a range of solvents commonly employed in SIBs, unlike NaClO4 and NaPF6, which exhibit solvent-dependent performances. Additionally, NaDFOB is stable and does not produce any toxic or hazardous substances upon contact with air and water. A recent study found that the incorporation of NaDFOB as an additive significantly enhances the charge-discharge capacity and cycling performance of graphite anodes. Another study suggests that NaDFOB contributes to the formation of a stable solid electrolyte interphase (SEI) film on the surface of graphite anodes, resulting in a highly stable electrolyte/electrode interface. With these benefits, Sodium-difluoro(oxalato)borate is a promising solution for improving the performance and stability of sodium-ion batteries in various applications.
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Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Sodium Difluoro(oxalato)borate as An Electrolyte Additive to Improve the Electrochemical Performance of Graphite Anode
Yang-yang Yao, et al.
International Journal of Electrochemistry, 21, 387-392 (2015)
