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217247

Sodium thiosulfate pentahydrate

ACS reagent, ≥99.5%

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About This Item

Linear Formula:
Na2S2O3 · 5H2O
CAS Number:
Molecular Weight:
248.18
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-867-5
MDL number:
Assay:
≥99.5%
Grade:
ACS reagent
Form:
crystalline powder, crystals, pellets
Solubility:
water: soluble(lit.)
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grade

ACS reagent

Quality Level

agency

suitable for EPA 1621, suitable for ISO 25101, suitable for SM 2310, suitable for SM 2320, suitable for SM 4500 - NH3

assay

≥99.5%

form

crystalline powder, crystals, pellets

impurities

≤0.002% N compounds, ≤0.005% insolubles

pH

6.0-8.4 (25 °C, 5%)

solubility

water: soluble(lit.)

anion traces

S2-: passes test, SO42- and SO32-: ≤0.1%

cation traces

N: ≤0.002%

application(s)

PFAS testing

SMILES string

O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=S

InChI

1S/2Na.H2O3S2.5H2O/c;;1-5(2,3)4;;;;;/h;;(H2,1,2,3,4);5*1H2/q2*+1;;;;;;/p-2

InChI key

PODWXQQNRWNDGD-UHFFFAOYSA-L

General description

Sodium thiosulfate pentahydrate is a hydrated form of sodium thiosulfate. It is used as a sulfur source for the preparation of various organosulfur compounds.

Application

Applied in a widely useful, thiosulfate-assisted, synthesis of a variety of diamine-CuCN complexes.
Sodium thiosulfate pentahydrate can be used as a sulfur source to synthesize:      
  • Thioester derivatives via one-pot two-step reactions with organic halides and aryl anhydrides.      
  • Sulfur nanoparticles using F. benghalensis leaf extract which acts as a reducing and capping agent.      
  • Unsymmetrical heteroaryl thioethers via multicomponent reaction with heteroaryl chlorides and alcohols.

It can also be used in the fabrication of microencapsulated phase change materials for thermal energy storage applications.

Features and Benefits

Na2S2O3 5H2O is a low toxic and odorless reagent that can be easily used in large-scale operations.


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Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Nuclear magnetic resonance in sodium thiosulfate pentahydrate.
Murty CRK and El Saffar ZM.
Acta Crystallographica, 15(6), 536-538 (1962)
Sodium thiosulfate pentahydrate: a redetermination by neutron diffraction.
Lisensky GC and Levy HA.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 34(6), 1975-1977 (1978)
Fingerprint imaging by scanning electrochemical microscopy.
Zhang M and Girault HH.
Electrochemical Communications, 9(7), 1778-1782 (2007)