214698
Pyridinium dichromate
98%
Sinónimos:
PDC
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Fórmula empírica (notación de Hill):
C10H10N2 · H2Cr2O7
Número CAS:
Peso molecular:
376.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
243-478-8
MDL number:
Assay:
98%
Form:
solid
Servicio técnico
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assay
98%
form
solid
reaction suitability
reagent type: oxidant
mp
152-153 °C (lit.)
SMILES string
c1ccncc1.c2ccncc2.O[Cr](=O)(=O)O[Cr](O)(=O)=O
InChI
1S/2C5H5N.2Cr.2H2O.5O/c2*1-2-4-6-5-3-1;;;;;;;;;/h2*1-5H;;;2*1H2;;;;;/q;;2*+1;;;;;;;/p-2
InChI key
RCBVKBFIWMOMHF-UHFFFAOYSA-L
General description
Pyridinium dichromate is a pyridinium salt and strong oxidizing agent to convert primary alcohols and secondary alcohols to aldehydes and ketones respectively.
Application
Oxidizing agent for conversion of primary alcohols to aldehydes and ketones, acetals to esters, and didehydroketones to enones in the presence of tert-butyl hydroperoxide (cat. no. 213128).
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Skin Sens. 1
Clase de almacenamiento
4.1A - Other explosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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J. Mol. Catal. A: Chem., 250, 70-70 (2006)
K M Halkes et al.
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