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Merck

H1006

Heptafluorobutyric anhydride

≥98%

Sinónimos:

HFAA, HFBA, Perfluorobutyric anhydride

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Fórmula lineal:
(CF3CF2CF2CO)2O
Número CAS:
Peso molecular:
410.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-410-8
Beilstein/REAXYS Number:
856036
MDL number:
Assay:
≥98%
Form:
liquid
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Quality Level

assay

≥98%

form

liquid

refractive index

n20/D 1.287 (lit.)

bp

108-110 °C (lit.)

mp

−43 °C (lit.)

density

1.674 g/mL at 20 °C (lit.)

storage temp.

room temp

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C8F14O3/c9-3(10,5(13,14)7(17,18)19)1(23)25-2(24)4(11,12)6(15,16)8(20,21)22

InChI key

UFFSXJKVKBQEHC-UHFFFAOYSA-N

Application

Heptafluorobutyric anhydride can be used as a derivatizing agent for the determination of:
  • Alkylphenol ethoxylates and brominated flame retardants in sewage sludge samples.
  • Free amino acids in sugarcane by GC analysis.

Packaging

5ML and 25ML in glass bottle

10 AMP in ampule


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Clase de almacenamiento

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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An integrated method for the simultaneous determination of alkylphenol ethoxylates and brominated flame retardants in sewage sludge samples by ultrasonic-assisted extraction, solid phase clean-up, and GC-MS analysis
Chokwe T, et al.
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 123, 230-236 (2015)
C Fakt et al.
Journal of chromatography. B, Biomedical sciences and applications, 700(1-2), 93-100 (1997-12-09)
A convenient and sensitive method for the quantitative determination of poly(ethylene glycol) 400 in plasma and urine with capillary gas chromatography-mass spectrometry has been developed. The sample preparation involves solid-phase extraction with subsequent derivatization with heptafluorobutyric anhydride, which proved to
Oliver Lerch et al.
Journal of chromatography. A, 991(1), 77-97 (2003-04-22)
Methods for ultra trace detection of endocrine disruptive chemicals (EDCs) are needed because of their low levels of impact. Twenty-one EDCs were selected, including 17beta-estradiol, 17alpha-ethinylestradiol, 17beta-testosterone and bisphenol A. Derivatisation with eight different fluorine containing compounds was examined. All