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Merck

12634

Potassium chlorate

puriss., 99-101%

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Fórmula lineal:
KClO3
Número CAS:
Peso molecular:
122.55
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
223-289-7
MDL number:
Assay:
99-101%
Form:
powder or crystals
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grade

puriss.

Quality Level

assay

99-101%

form

powder or crystals

impurities

≤0.001% heavy metals (as Pb)

pH

5-6.5 (25 °C, 61.3 g/L)

mp

356 °C (lit.)

anion traces

chloride (Cl-): ≤100 mg/kg, sulfate (SO42-): ≤100 mg/kg

cation traces

As: ≤2 mg/kg, Ca: ≤50 mg/kg, Fe: ≤30 mg/kg

SMILES string

[K+].[O-]Cl(=O)=O

InChI

1S/ClHO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1

InChI key

VKJKEPKFPUWCAS-UHFFFAOYSA-M

General description

Crystals of potassium chlorate belong to the monoclinic crystal system. On heating above 400°C, it degrades to give potassium chloride and potassium perchlorate. It has strong oxidizing properties. On exposure to X-rays, oxygen-17 enriched KClO3 generates O3- radical, which was investigated by ESR (Electron Spin Resonance). Irradiation of potassium chlorate with X-ray causes the degradation to generate chloride, chlorite, hypochlorite and occluded oxygen. Significant quantities of dichlorine hexoxide and a trace of chlorine dioxide were also produced.

Application

Potassium chlorate may be used in the preparation of graphite oxide (GO).


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pictograms

Flame over circleSkull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Ox. Sol. 1

Clase de almacenamiento

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable



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Arda Gülay et al.
mBio, 10(6) (2019-11-07)
Nitrification, the oxidative process converting ammonia to nitrite and nitrate, is driven by microbes and plays a central role in the global nitrogen cycle. Our earlier investigations based on 16S rRNA and amoA amplicon analysis, amoA quantitative PCR and metagenomics
The Decomposition of Solid Potassium Chlorate by X Rays.
Heal HG.
Canadian Journal of Chemistry, 37(5), 979-987 (1959)
Single sheet functionalized graphene by oxidation and thermal expansion of graphite.
McAllister MJ, et al.
Chemistry of Materials, 19(18), 4396-4404 (2007)