161527
Sodium hydrosulfide hydrate
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Fórmula lineal:
NaSH·xH2O
Número CAS:
Peso molecular:
56.06 (anhydrous basis)
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
chips, flakes
Servicio técnico
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form
chips, flakes
concentration
≥60% (by Na2S2O3, titration)
mp
52-54 °C (lit.)
SMILES string
[Na]S.[H]O[H]
InChI
1S/Na.H2O.H2S/h;2*1H2/q+1;;/p-1
InChI key
ZNKXTIAQRUWLRL-UHFFFAOYSA-M
General description
Sodium hydrosulfide hydrate is a hydrated inorganic salt of sodium. It participates in the synthesis of (E)-2-cyano-2-(thiazolidin-2-ylidene)ethanethioamide.
Application
It may be used as a sulfur nucleophile to induce the C-S bond formation in α,β-dichloro vinyl ketones to form 5- to 8-membered cyclic thioethers.
Sodium hydrosulfide hydrate may be used in the synthesis of following:
- benzothiazole
- 4-methoxybenzothioamide
- 2-(4-methoxyphenyl)imidazoline
- 7-chloro-4′-methoxythioflavone
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B
Clase de almacenamiento
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
flash_point_f
194.0 °F - closed cup
flash_point_c
90 °C - closed cup
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