237051
Aluminum chloride
ReagentPlus®, 99%
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Fórmula lineal:
AlCl3
Número CAS:
Peso molecular:
133.34
PubChem Substance ID:
eCl@ss:
38120507
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
231-208-1
MDL number:
Assay:
99%
Form:
powder
Servicio técnico
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Permítanos ayudarlevapor pressure
1 mmHg ( 100 °C)
Quality Segment
product line
ReagentPlus®
assay
99%
form
powder
reaction suitability
reagent type: catalyst
core: aluminum
pH
2.4 (20 °C, 100 g/L)
mp
190 °C (lit.)
SMILES string
Cl[Al](Cl)Cl
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
InChI key
VSCWAEJMTAWNJL-UHFFFAOYSA-K
General description
Aluminum chloride is an alcohol-soluble lewis acid.† Aluminum chloride mixed with sodium borohydride, in diglyme in a molar ratio affords a mixture having strong reducing properties.† It was reported to promote the Friedel-Crafts acylation reaction between 4-tert-butylbenzoyl chloride and mesitylene.†
Application
Aluminum chloride was used for the following studies:
- Polymerization of benzene to afford p-polyphenyl.
- As a catalyst for the Friedel-Crafts acylation of buckymetallocenes with the acid chlorides.
- As a catalyst for the colorimetric microassay for the determination of lipid hydroperoxides.
Features and Benefits
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
Clase de almacenamiento
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)
p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused