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Merck

239305

Sodium hypochlorite solution

greener alternative

reagent grade, available chlorine 4.00-4.99 %

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Fórmula lineal:
NaClO
Número CAS:
7681-52-9
Peso molecular:
74.44
NACRES:
NA.21
PubChem Substance ID:
329752526
UNSPSC Code:
12352300
EC Number:
231-668-3
MDL number:
MFCD00011120

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Nombre del producto

Sodium hypochlorite solution, reagent grade, available chlorine 4.00-4.99 %

InChI key

SUKJFIGYRHOWBL-UHFFFAOYSA-N

InChI

1S/ClO.Na/c1-2;/q-1;+1

SMILES string

[Na+].[O-]Cl

grade

reagent grade

agency

suitable for SM 4500 - NH3

vapor pressure

17.5 mmHg ( 20 °C)

form

liquid

composition

available chlorine, 4.00-4.99%

reaction suitability

reagent type: oxidant

greener alternative product characteristics

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

4.00-4.99% (chlorine by Na2S2O3, titration)

density

1.097 g/mL at 25 °C

greener alternative category

Aligned

storage temp.

2-8°C

Quality Level

100

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Application

Sodium hypochlorite solution can be used as an oxidizing agent for the oxidation of:      
  • Primary alcohols to aldehydes or carboxylic acids and secondary alcohols to ketones.     
  • Aryl aldehydes to the corresponding acids in the presence of a phase-transfer catalyst.      
  • Ethers to esters by careful pH control (pH range of 8–9.5),

It can also be used as a reagent in the:      
  • Epoxidation of enones and polycyclic arenes.      
  • Oxidative degradation reaction      
  • N-Chlorination of primary and secondary amines
  • Enantioselective epoxidation of α, β-unsaturated ketones      
  • Asymmetric dihydroxylation of olefins in the presence of an osmium catalyst      
  • Chlorination of allylic carbons in the presence of CeCl3

Disclaimer

“The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others.”

Features and Benefits

  • Readily available reagent      
  • Easily handled oxidizing agent      
  • No phase-transfer catalyst is necessary for the oxidation of substrates in the pH range 10–11     
  • Simplified waste disposal and lower toxicity

General description

Sodium hypochlorite (NaOCl) is a commonly used reagent in organic synthesis for many oxidation and chlorination reactions.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product is considered as an environmentally benign oxidant and has been enhanced for "Safer Solvents and Auxiliaries". Click here for more information.

pictograms

CorrosionEnvironment
GHS05,GHS09

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2

Clase de almacenamiento

12 - Non Combustible Liquids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
SHBL1783
SHBN8920
SHBN7481
SHBL9361
SHBN4973

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Arabidopsis thaliana TRY is a negative regulator of trichome differentiation that promotes root hair differentiation. Here, we established that LbTRY, from the recretohalophyte Limonium bicolor, is a typical MYB transcription factor that exhibits transcriptional activation activity and locates in nucleus.
In vivo evaluation of chlorhexidine gluconate solution and sodium hypochlorite solution as root canal irrigants.
A M Ringel et al.
Journal of endodontics, 8(5), 200-204 (1982-05-01)
B R Johnson et al.
Journal of endodontics, 19(1), 40-43 (1993-01-01)
Although the tissue solvent and bactericidal properties of sodium hypochlorite are well known, the effective shelf-life of prepared sodium hypochlorite solutions is not known. The stability of sodium hypochlorite is adversely affected by exposure to high temperature, light, air, and
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