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Merck

366374

Zinc chloride solution

0.5 M in THF

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Fórmula lineal:
ZnCl2
Número CAS:
7646-85-7
Peso molecular:
136.30
NACRES:
NA.55
PubChem Substance ID:
329755428
UNSPSC Code:
12352302
MDL number:
MFCD00011295
Form:
liquid

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InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

SMILES string

Cl[Zn]Cl

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

form

liquid

concentration

0.5 M in THF, 470-600 mmol/L (silver nitrate titration)

density

0.948 g/mL at 25 °C

Quality Level

100

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General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Clase de almacenamiento

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

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Certificados de análisis (COA)

Lot/Batch Number
SHBL9069
SHBH1037V
SHBD0457V
SHBC1890V
SHBB8411V

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. Why does the MSDS for Product 366374 - 0.5M Zinc Chloride solution in THF state the prdouct may form explosive peroxides?

    Zinc Chloride is not a peroxide former itself but since its mixed with THF, THF is a peroxide former.

  6. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Zinc chloride-catalyzed chloromethylation of resins for solid phase peptide synthesis.
Feinberg RS and Merrifield RB.
Tetrahedron, 30(17), 3209-3212 (1974)
Versatile palladium (II)-catalyzed Negishi coupling reactions with functionalized conjugated alkenyl chlorides.
Peyrat JF, et al.
Tetrahedron Letters, 44(35), 6703-6707 (2003)
Thin-layer electrochemistry of ferrocenylbenzene derivatives: Intramolecular electronic communication.
Wang MCP, et al.
Electrochimica Acta, 53(26), 7720-7725 (2008)
Michele K Sankako et al.
Pharmacological reports : PR, 64(6), 1537-1546 (2013-02-15)
The aim of this study was to evaluate the changes in testicular function of rats due to cigarette smoke exposure and the possible mechanism by which zinc protects against these alterations. Male Wistar rats (60 days old) were randomly divided
Hai-Long Jiang et al.
Journal of the American Chemical Society, 134(36), 14690-14693 (2012-08-22)
Reactions of ZrCl(4) and single or mixed linear dicarboxylic acids bearing methyl or azide groups lead to highly stable isoreticular metal-organic frameworks (MOFs) with content-tunable, accessible, reactive azide groups inside the large pores. These Zr-based MOFs offer an ideal platform
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