189871
エチルマグネシウムブロミド 溶液
3.0 M in diethyl ether
別名:
EtMgBr溶液
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この商品について
化学式:
CH3CH2MgBr
CAS番号:
分子量:
133.27
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Beilstein/REAXYS Number:
3587203
MDL number:
製品名
エチルマグネシウムブロミド 溶液, 3.0 M in diethyl ether
SMILES string
[CC[Mg]Br]
CC[Mg]Br
InChI key
[HSNUIYJWTSJUMS-UHFFFAOYSA-N]
TWTWFMUQSOFTRN-UHFFFAOYSA-M
InChI
[1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1]
1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
3.0 M in diethyl ether
bp
34.6 °C/1.013 hPa
density
1.02 g/mL at 25 °C
Quality Level
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Application
エチルマグネシウムブロマイド溶液（3.0 M、ジエチルエーテル溶液）は、銅（I）触媒によるアリル置換反応に使用できます。
General description
有機マグネシウム化合物であるエチルマグネシウムブロマイドは、グリニャール試薬として一般的に知られています。主にC-C結合形成に使用される強力な炭素求核剤です。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Respiratory system
supp_hazards
保管分類
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
-40.0 °F - closed cup
flash_point_c
-40 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Enantioselective Copper-Catalyzed SN2? Substitution with Grignard Reagents.
Alexakis A, et al.
Synlett, 0927-0930 (2001)
Organic Chemistry, 542-542 (2008)
M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
R G Xie et al.
Steroids, 55(11), 488-490 (1990-11-01)
The reaction of ethyl magnesium bromide and 17 alpha-ethynylestradiol with formaldehyde in the presence of triethyl phosphate or hexamethylphosphoramide gave the 2- and 4-formyl-17 alpha-ethynylestradiol in high yield. Treatment of the formyl derivatives with an alkaline solution of hydrogen peroxide
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