122793
Allyl cyanide
98%
동의어(들):
3-Butenenitrile, Vinylacetonitrile
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
CH2=CHCH2CN
CAS 번호:
Molecular Weight:
67.09
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
203-701-1
Beilstein/REAXYS Number:
605352
MDL number:
Quality Level
assay
98%
autoignition temp.
851 °F
refractive index
n20/D 1.405 (lit.)
bp
116-121 °C (lit.)
density
0.834 g/mL at 25 °C (lit.)
SMILES string
C=CCC#N
InChI
1S/C4H5N/c1-2-3-4-5/h2H,1,3H2
InChI key
SJNALLRHIVGIBI-UHFFFAOYSA-N
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
저장 등급
3 - Flammable liquids
wgk
WGK 3
flash_point_f
75.2 °F - closed cup
flash_point_c
24 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Ryo Yazaki et al.
Journal of the American Chemical Society, 130(44), 14477-14479 (2008-10-11)
Direct catalytic asymmetric addition of allylic cyanides to N-diphenylphosphinoyl ketoimines with a bimetallic catalytic system comprising Ph-BPE/[Cu(CH3CN)4]ClO4/LiOAr is described. Intermediary alpha-adducts readily isomerized to afford synthetically useful alpha,beta-unsaturated nitriles bearing an optically active tetrasubstituted carbon. Applicability to aromatic, heteroaromatic, and
Katja Witzel et al.
PloS one, 8(9), e71877-e71877 (2013-09-17)
The soil-borne fungal pathogen Verticillium longisporum is able to penetrate the root of a number of plant species and spread systemically via the xylem. Fumigation of Verticillium contaminated soil with Brassica green manure is used as an environmentally friendly method
Asymmetric synthesis of isothiazoles through Cu catalysis: direct catalytic asymmetric conjugate addition of allyl cyanide to α,β-unsaturated thioamides.
Yuka Yanagida et al.
Angewandte Chemie (International ed. in English), 50(34), 7910-7914 (2011-07-07)