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Merck

190144

Pyridinium chlorochromate

98%

동의어(들):

PCC

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
C5H6NClCrO3
CAS 번호:
Molecular Weight:
215.56
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
247-595-5
Beilstein/REAXYS Number:
7054643
MDL number:
Assay:
98%
Form:
solid
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Quality Level

assay

98%

form

solid

reaction suitability

reagent type: oxidant

mp

205-208 °C (lit.)

SMILES string

O[Cr](Cl)(=O)=O.c1ccncc1

InChI

1S/C5H5N.ClH.Cr.H2O.2O/c1-2-4-6-5-3-1;;;;;/h1-5H;1H;;1H2;;/q;;+2;;;/p-2

InChI key

JWIPGAFCGUDKEY-UHFFFAOYSA-L

General description

PCC is an important organic reagent used for oxidation reactions.

Application

Stable versatile oxidizing agent for mild and selective oxidation of alcohols.
Used to oxidize an allylic methylene group in a synthesis of α,β-unsaturated lactones from D-glucose using Grubbs-catalyzed ring-closing metathesis.


signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Ox. Sol. 2 - Skin Sens. 1

저장 등급

5.1B - Oxidizing hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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문서 라이브러리 방문


문서

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis


Anna M Larsson et al.
Journal of experimental botany, 68(14), 3857-3867 (2017-04-04)
Cyanobacterial CO2 fixation is promoted by encapsulating and co-localizing the CO2-fixing enzymes within a protein shell, the carboxysome. A key feature of the carboxysome is its ability to control selectively the flux of metabolites in and out of the shell.
Tetrahedron, 62, 11165-11165 (2006)
Cheryl Peters et al.
Pediatric critical care medicine : a journal of the Society of Critical Care Medicine and the World Federation of Pediatric Intensive and Critical Care Societies, 19(8), e394-e402 (2018-06-26)
We evaluated adapting the quick Sequential (Sepsis-Related) Organ Failure Assessment score (fast respiratory rate, altered mental status, low blood pressure) for pediatric use by selecting thresholds from three commonly used definitions: Pediatric Logistic Organ Dysfunction 2, Pediatric Advanced Life Support