236071
N,N′-Bis(salicylidene)ethylenediamine
98%
동의어(들):
2,2′-Ethylenebis(nitrilomethylidene)diphenol, N,N′-Ethylenebis(salicylimine)
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
(CH2N=CHC6H4OH)2
CAS 번호:
Molecular Weight:
268.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-376-3
Beilstein/REAXYS Number:
535296
MDL number:
Assay:
98%
Quality Level
assay
98%
mp
127-128 °C (lit.)
solubility
water: insoluble(lit.)
functional group
amine, imine
SMILES string
Oc1ccccc1\C=N\CC\N=C\c2ccccc2O
InChI
1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+
InChI key
VEUMANXWQDHAJV-JYFOCSDGSA-N
관련 카테고리
General description
N,N′-Bis(salicylidene)ethylenediamine (salen) reacts with ferric chloride in acetone solution to yield the complex (Fe salen Cl).
Application
N,N′-Bis(salicylidene)ethylenediamine (salen) immobilized on surfactant-coated alumina has been used as complexing agent for on-line preconcentration of copper and lead by flow injection-flame atomic absorption spectrometry (FI-AAS).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
저장 등급
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Structure and Paramagnetism of Five-and Six-Co-ordinate N: N' Bis-salicylidene Ethylenediamine Iron (III) Chloride.
Gerloch M, et al.
Nature, 212, 809-810 (1966)
Linus Chiang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(44), 14117-14127 (2012-09-22)
Square-planar nickel(II) complexes of salen ligands, N,N'-bis(3-tert-butyl-(5R)-salicylidene)-1,2-cyclohexanediamine), in which R=tert-butyl (1), OMe (2), and NMe(2) (3), were prepared and the electronic structure of the one-electron-oxidized species [1-3](+·) was investigated in solution. Cyclic voltammograms of [1-3] showed two quasi-reversible redox waves
F Janati Fard et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 74-82 (2012-07-04)
Co(III) salen complex with N,N'-dipyridoxyl (1,4-butanediamine) Schiff-base ligand as tetradentate ligand was synthesized and characterized by the elemental and spectroscopic analysis. The interaction of this complex with calf thymus DNA (ct DNA) has been investigated in vitro using UV absorption
Teng Zhang et al.
Chemical communications (Cambridge, England), 48(70), 8766-8768 (2012-07-28)
Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.
David J Burns et al.
Organic & biomolecular chemistry, 10(38), 7666-7668 (2012-08-30)
Due to the lack of availability of unnatural (+)-quinic acid as a starting material, a 6-step synthesis of butane diacetal-protected (4S,5S)-dihydroxycyclohexen-1-one (formally derived from (+)-quinic acid) has been devised. The key catalytic asymmetric step involves a chiral Co-salen-catalysed epoxide ring-opening
문서
Nitric oxide (NO) as a signal transporter in neurons, endothelial cells and in the immune system.
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