243086
Pyridine hydrochloride
98%
동의어(들):
Pyridinium chloride
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C5H5N · HCl
CAS 번호:
Molecular Weight:
115.56
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39151701
UNSPSC Code:
12352100
EC Number:
211-027-4
MDL number:
Beilstein/REAXYS Number:
3615340
Assay:
98%
InChI key
AOJFQRQNPXYVLM-UHFFFAOYSA-N
InChI
1S/C5H5N.ClH/c1-2-4-6-5-3-1;/h1-5H;1H
SMILES string
Cl[H].c1ccncc1
assay
98%
bp
222-224 °C (lit.)
mp
145-147 °C (lit.)
solubility
ethanol: soluble 50 mg/mL, clear, colorless to light yellow
Quality Level
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General description
Pyridine hydrochloride is an acidic type demethylating agent used as a catalyst in deprotection of aromatic methyl ethers.
Application
Pyridine hydrochloride (pyridine hydrochloride) was used in the demethylation of 4,5-dimethyl-7-methoxy-1-tetralone.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
저장 등급
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Demethylation of methyl aryl ethers using pyridine hydrochloride in solvent-free conditions under microwave irradiation.
Kulkarni PP, et al.
J. Chem. Res. Synop., 6, 394-395 (1999)
Tatyana N Sevastyanova et al.
Molecular pharmacology, 86(5), 492-504 (2014-08-13)
Metabotropic glutamate receptors (mGluRs) function as dimers. Recent work suggests that mGluR1 and mGluR5 may physically interact, but the nature and functional consequences of this relationship have not been addressed. In this study, the functional and pharmacological consequences of this
Nathalie Ségaud et al.
Inorganic chemistry, 52(2), 691-700 (2013-01-11)
We report the synthesis, characterization, and solution chemistry of a series of new Fe(II) complexes based on the tetradentate ligand N-methyl-N,N'-bis(2-pyridyl-methyl)-1,2-diaminoethane or the pentadentate ones N,N',N'-tris(2-pyridyl-methyl)-1,2-diaminoethane and N,N',N'-tris(2-pyridyl-methyl)-1,3-diaminopropane, modified by propynyl or methoxyphenyltriazolyl groups on the amino functions. Six of
Jipan Yu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4271-4277 (2013-02-13)
Efficient copper-catalyzed aerobic oxidative C-H and C-C functionalization of 1-[2-(arylamino)aryl]ethanones leading to acridones has been developed. The procedure involves cleavage of aromatic C-H and acetyl C-C bonds with intramolecular formation of a diarylketone bond. The protocol uses inexpensive Cu(O2CCF3)2 as
Ye Wei et al.
Journal of the American Chemical Society, 135(10), 3756-3759 (2013-02-27)
We describe here a [3+3]-type condensation reaction of O-acetyl ketoximes and α,β-unsaturated aldehydes that is synergistically catalyzed by a copper(I) salt and a secondary ammonium salt (or amine). This redox-neutral reaction allows modular synthesis of a variety of substituted pyridines
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