302341
Acetoxyacetic acid
99%
동의어(들):
α-Acetoxyacetic acid, (Acetyloxy)acetic acid, 2-(Acetyloxy)acetic acid, 2-Hydroxyacetic acid acetate, Acetylglycolic acid, O-Acetylglycolic acid
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
CH3CO2CH2CO2H
CAS 번호:
Molecular Weight:
118.09
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
237-541-9
MDL number:
Assay:
99%
Quality Level
assay
99%
bp
141-142 °C/12 mmHg (lit.)
mp
67-69 °C (lit.)
functional group
carboxylic acid, ester
SMILES string
CC(=O)OCC(O)=O
InChI
1S/C4H6O4/c1-3(5)8-2-4(6)7/h2H2,1H3,(H,6,7)
InChI key
MLXDUYUQINCFFV-UHFFFAOYSA-N
General description
Acetoxyacetic acid is kinetically stable degradation product of oxidative degradation of 1,3-dialkylimidazolium ionic liquids in hydrogen peroxide/aceticacid aqueous medium assisted by ultrasonic chemical irradiation. It is an intermediate formed during reactions of manganic acetate in glacial acetic acid with benzene (100°C), chlorobenzene, or toluene.
Application
Acetoxyacetic acid was used in preparation of tert-butyl glycolate.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
저장 등급
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Synthetic studies of pyridomycin. II. Synthesis of a model twelve-membered ring compound related to pyridomycin.
Kinoshita M and Awamura M.
Bulletin of the Chemical Society of Japan, 51(3), 869-871 (1978)
Intermediate steps in autoxidation: III. Reactions of MnIII acetate in acetic acid with benzene, chlorobenzene, and toluene.
Van der PRE, et al.
J. Catal., 10(1), 52-59 (1968)
Xuehui Li et al.
Dalton transactions (Cambridge, England : 2003), (19)(19), 1875-1880 (2007-08-19)
A highly efficient process for oxidative degradation of 1,3-dialkylimidazolium ionic liquids in hydrogen peroxide/acetic acid aqueous medium assisted by ultrasonic chemical irradiation is, for the first time, described. It is shown that more than 93% of the 1,3-dialkylimidazolium cation with