์ฝ˜ํ…์ธ ๋กœ ๊ฑด๋„ˆ๋›ฐ๊ธฐ
Merck

455571

Potassium borohydride

≥97%

๋™์˜์–ด(๋“ค):

Potassium tetrahydroborate

์กฐ์ง ๋ฐ ๊ณ„์•ฝ ๊ฐ€๊ฒฉ์„ ๋ณด๋ ค๋ฉด ๋กœ๊ทธ์ธ๋ฅผ ํด๋ฆญํ•ฉ๋‹ˆ๋‹ค.

ํฌ๊ธฐ ์„ ํƒ

๋ณด๊ธฐ ๋ณ€๊ฒฝ

์ œํ’ˆ์ •๋ณด (DICE ๋ฐฐ์†ก ์‹œ ๋น„์šฉ ๋ณ„๋„)

Linear Formula:
KBH4
CAS ๋ฒˆํ˜ธ:
Molecular Weight:
53.94
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352306
EC Number:
237-360-5
MDL number:
Assay:
≥97%
Form:
powder
๊ธฐ์ˆ  ์„œ๋น„์Šค
๋„์›€์ด ํ•„์š”ํ•˜์‹ ๊ฐ€์š”? ์ €ํฌ ์ˆ™๋ จ๋œ ๊ณผํ•™์ž ํŒ€์ด ๋„์™€๋“œ๋ฆฌ๊ฒ ์Šต๋‹ˆ๋‹ค.
๋„์›€ ๋ฌธ์˜


Quality Level

assay

≥97%

form

powder

reaction suitability

reagent type: reductant

mp

500 ยฐC (dec.) (lit.)

density

1.18 g/mL at 25 ยฐC (lit.)

SMILES string

[K+].[H][B-]([H])([H])[H]

InChI

1S/BH4.K/h1H4;/q-1;+1

InChI key

ICRGAIPBTSPUEX-UHFFFAOYSA-N

Application

Potassium borohydride (KBH4) can be used as a reducing agent for the synthesis of:ย ย ย ย ย ย ย 
  • Copper nanoparticles by the reduction of copper salts.
  • ย Enantioselective allylic alcohols by the catalytic reduction of enones and ketones in the presence of chiral N,Nโ€ฒ-dioxidescandium(III) complex catalyst.,ฮ‡ย ย ย ย ย ย ย ย 
  • Azoxybenzenes by the reduction of nitroarenes in the presence of phase transfer catalyst PEG-400.

It can also be employed as a boron source in the nickelโ€“boron alloy, which is electrodeposited on carbon fiber to improve catalytic graphitization of carbon.


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signalword

Danger

์ €์žฅ ๋“ฑ๊ธ‰

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react. 1



๊ฐ€์žฅ ์ตœ์‹  ๋ฒ„์ „ ์ค‘ ํ•˜๋‚˜๋ฅผ ์„ ํƒํ•˜์„ธ์š”:

์‹œํ—˜ ์„ฑ์ ์„œ(COA)

Lot/Batch Number

์ ํ•ฉํ•œ ๋ฒ„์ „์„ ์ฐพ์„ ์ˆ˜ ์—†์œผ์‹ ๊ฐ€์š”?

ํŠน์ • ๋ฒ„์ „์ด ํ•„์š”ํ•œ ๊ฒฝ์šฐ ๋กœํŠธ ๋ฒˆํ˜ธ๋‚˜ ๋ฐฐ์น˜ ๋ฒˆํ˜ธ๋กœ ํŠน์ • ์ธ์ฆ์„œ๋ฅผ ์ฐพ์„ ์ˆ˜ ์žˆ์Šต๋‹ˆ๋‹ค.

์ด ์ œํ’ˆ์„ ์ด๋ฏธ ๊ฐ€์ง€๊ณ  ๊ณ„์‹ญ๋‹ˆ๊นŒ?

๋ฌธ์„œ ๋ผ์ด๋ธŒ๋Ÿฌ๋ฆฌ์—์„œ ์ตœ๊ทผ์— ๊ตฌ๋งคํ•œ ์ œํ’ˆ์— ๋Œ€ํ•œ ๋ฌธ์„œ๋ฅผ ์ฐพ์•„๋ณด์„ธ์š”.

๋ฌธ์„œ ๋ผ์ด๋ธŒ๋Ÿฌ๋ฆฌ ๋ฐฉ๋ฌธ



S. Yan and S. Zhang,
International Journal of Hydrogen Energy, 36, 13392-13397 (2011)
A. Yin, et al.,
Applied Catalysis, 400, 39-47 (2011)
Gang Lian et al.
Dalton transactions (Cambridge, England : 2003), 40(26), 6961-6967 (2011-06-07)
Cubic boron nitride (cBN) is synthesized by a low-temperature solid state synthesis and in situ phase transformation route with NH(4)BF(4), B, NaBH(4) and KBH(4) as the boron sources and NaN(3) as the nitrogen source. Furthermore, two new strategies are developed