458139
tert-Butyl hydroperoxide solution
70 wt. % in H2O
동의어(들):
TBHP, 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
(CH3)3COOH
CAS 번호:
Molecular Weight:
90.12
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1098280
form
liquid
Quality Level
reaction suitability
reaction type: C-H Activation, reagent type: catalyst, reagent type: oxidant
concentration
12.25-13.31% (active oxygen), 69.0-75.0% (Na2S2O3, titration), 70 wt. % in H2O
refractive index
n20/D 1.386
pH
4.3
bp
96.2 °C
density
0.93 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
Application
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Versatile reagent for oxidations.
Legal Information
Product of Arkema Inc.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
저장 등급
5.2 - Organic peroxides and self-reacting hazardous materials
flash_point_f
107.6 °F - closed cup
flash_point_c
42 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
J. Chem. Res. Synop., 7, 390-394 (2003)
Inorgorganica Chimica Acta, 357, 2237-2244 (2004)
J. Catal., 224, 288-296 (2004)