631868
1,4-Dioxane solution
suitable for NMR (reference standard), 5 mM in chloroform-d (99.8 atom % D), NMR tube size 3 mm × 8 in.
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C4H8O2
CAS 번호:
Molecular Weight:
88.11
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
12142201
MDL number:
InChI
1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2
SMILES string
C1COCCO1
InChI key
RYHBNJHYFVUHQT-UHFFFAOYSA-N
grade
analytical standard
concentration
5 mM in chloroform-d (99.8 atom % D)
technique(s)
NMR: suitable
NMR tube size
3 mm × 8 in.
density
1.500 g/mL at 25 °C
suitability
suitable for NMR (reference standard)
format
single component solution
Quality Level
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General description
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)
Preparation Note
3 mm O.D. tube contains 0.235 mL.
Each pack contains 10 tubes.
Each pack contains 10 tubes.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
target_organs
Central nervous system, Liver,Kidney
저장 등급
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
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Reaction conditions for the CC cross-coupling of O(6)-alkyl-2-bromo- and 2-chloroinosine derivatives with aryl-, hetaryl-, and alkylboronic acids were studied. Optimization experiments with silyl-protected 2-bromo-O(6)-methylinosine led to the identification of [PdCl(2)(dcpf)]/K(3)PO(4) in 1,4-dioxane as the best conditions for these reactions (dcpf=1,1'-bis(dicyclohexylphosphino)ferrocene).
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Chemphyschem : a European journal of chemical physics and physical chemistry, 13(18), 4195-4201 (2012-10-24)
The quenching of pyrene and 1-methylpyrene fluorescence by nitroanilines (NAs), such as 2-, 3-, and 4-nitroaniline (2-NA, 3-NA, and 4-NA, respectively), 4-methyl-3-nitroaniline (4-M-3-NA), 2-methyl-4-nitroaniline (2-M-4-NA), and 4-methyl-3,5-dinitroaniline (4-M-3,5-DNA), are studied in toluene and 1,4-dioxane. Steady-state fluorescence data show the higher
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