710857
Iron(III) chloride solution
0.2 M in 2-methyltetrahydrofuran, solution
동의어(들):
Ferric chloride solution
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
FeCl3
CAS 번호:
Molecular Weight:
162.20
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
제품 이름
Iron(III) chloride solution, 0.2 M in 2-methyltetrahydrofuran
form
solution
Quality Level
reaction suitability
core: iron, reagent type: catalyst
greener alternative product characteristics
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
concentration
0.2 M in 2-methyltetrahydrofuran
refractive index
n20/D 1.414
density
0.868 g/mL at 25 °C
greener alternative category
, Aligned
SMILES string
Cl[Fe](Cl)Cl
InChI
1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI key
RBTARNINKXHZNM-UHFFFAOYSA-K
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl3 is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.
Application
Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used:
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
- As a mild oxidant for phenolic coupling reaction.
- In dimerizing aryllithiumsand ketone enolates.
- As a mild Lewis acid catalyst to catalyzes ene reactions.
- In Nazarov cyclizations, Michael additions, and acetonation reactions.
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2
supp_hazards
저장 등급
3 - Flammable liquids
wgk
WGK 2
flash_point_f
14.0 °F - closed cup
flash_point_c
-10.0 °C - closed cup
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
William H DePas et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(7), 2629-2634 (2013-01-30)
Bacterial biofilm formation is a complex developmental process involving cellular differentiation and the formation of intricate 3D structures. Here we demonstrate that exposure to ferric chloride triggers rugose biofilm formation by the uropathogenic Escherichia coli strain UTI89 and by enteric