F408
Ferrocene
98%
동의어(들):
Bis(cyclopentadienyl)iron, Di(cyclopentadienyl)iron
조직 및 계약 가격을 보려면 로그인를 클릭합니다.
크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
Fe(C5H5)2
CAS 번호:
Molecular Weight:
186.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
203-039-3
MDL number:
InChI
1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;
InChI key
DFRHTHSZMBROSH-UHFFFAOYSA-N
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
vapor pressure
0.03 mmHg ( 40 °C)
assay
98%
reaction suitability
core: iron, reagent type: catalyst
bp
249 °C (lit.)
Quality Level
λmax
358 nm
storage temp.
2-8°C
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Application
Ferrocene (dicyclopentadienyliron) can be used:
- As a scaffold for chiral ligands in asymmetric catalysis.
- In ferrocene-based electrolytes for dye sensitized solar cells applications.
- In the synthesis of unsymmetrical ferrocene ligands used as catalysts in cross-coupling, hydrogenation, allylic substitution, hydroformylation and aldol reactions.
- In the synthesis of two-dimensional hexagonally ordered mesoporous carbon (CMK-5) via chemical vapor deposition method, which is used as a catalyst support in oxidation of methanol.
- In the synthesis of molecular hybrids of ferrocene and fullerene (Bucky ferrocenes).
- In the preparation of ferrocenium salt which is used as a mild oxidant.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation
target_organs
Liver
저장 등급
4.1B - Flammable solid hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
The syntheses and catalytic applications of unsymmetrical ferrocene ligands
Atkinson RCJ, et al.
Chemical Society Reviews, 33(33), 313-328 (2004)
Muneebah Adams et al.
Dalton transactions (Cambridge, England : 2003), 42(13), 4677-4685 (2013-01-31)
A series of aryl-functionalized and ferrocenyl monothiosemicarbazone compounds (L1-L4) were synthesized in moderate yields via a general Schiff-base condensation reaction. The thiosemicarbazone (TSC) ligands were reacted with the ruthenium dimer [Ru(Ar)(μ-Cl)Cl](2) (Ar = benzene; p-cymene) to yield a series of
Sumit Kumar et al.
ACS omega, 3(9), 12106-12113 (2018-10-16)
1H-1,2,3-Triazole tethered imidazole-isatin and imidazole-isatin-thiosemicarbazone conjugates were synthesized and evaluated against MCF-7 and MDA-MB-231 cell lines. Antiproliferative activities of the synthesized conjugates revealed an optimum combination of longer alkyl chain length as spacer and a halogen-substituent on the isatin ring
Applications of ferrocenium salts in organic synthesis
Toma S and Sebesta R
Synthesis, 12(47), 1683-1695 (2015)
Hybrid of ferrocene and fullerene
Sawamura M, et al.
Journal of the American Chemical Society, 32(124), 9354-9355 (2002)
문서
Atomic layer deposition meets various needs including semiconductor device miniaturization and nanoparticle coating.
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