291056
Methyl formate
anhydrous, 99%
동의어(들):
Formic acid methyl ester
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
HCO2CH3
CAS 번호:
Molecular Weight:
60.05
UNSPSC Code:
12352108
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-481-7
Beilstein/REAXYS Number:
1734623
MDL number:
Assay:
99%
Grade:
anhydrous
Bp:
32-34 °C (lit.)
Vapor pressure:
32.91 psi ( 55 °C), 9.47 psi ( 20 °C)
InChI key
TZIHFWKZFHZASV-UHFFFAOYSA-N
InChI
1S/C2H4O2/c1-4-2-3/h2H,1H3
SMILES string
[H]C(=O)OC
grade
anhydrous
vapor density
2.1 (vs air)
vapor pressure
32.91 psi ( 55 °C), 9.47 psi ( 20 °C)
assay
99%
Quality Level
autoignition temp.
842 °F
expl. lim.
23 %
impurities
<0.005% water
evapn. residue
<0.0005%
refractive index
n20/D 1.343 (lit.)
pH
4-5 (20 °C, 200 g/L)
bp
32-34 °C (lit.)
mp
−100 °C (lit.)
density
0.974 g/mL at 20 °C (lit.)
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Application
Methyl formate may be used in the synthesis of the following building blocks:
- methyl 4-chloro-2-formylbutanoate from methyl 4-chlorobutanoate via -formylation
- potassium methyl α-[(methoxyethylidene)amino]-β-hydroxyacrylate from methyl α-[(methoxyethylidene)amino]acetate
- (S)-(-)-1-formyl-2-hydroxymethylpyrrolidine from (S)-(+)-2-hydroxymethylpyrrolidine via N-formylation
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3
target_organs
Respiratory system
저장 등급
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-2.2 °F - closed cup
flash_point_c
-19 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
(S)-(-)-1-Amino-2-Methoxymethylpyrrolidine (SAMP) and (R)-(+)-1-Amino-2-Methoxymethylpyrrolidine (RAMP), Versatile Chiral Auxiliaries
Enders D, et al.
Organic Syntheses, 65, 173-173 (1987)
Synthesis of Methyl 1-Formylcyclopropanecarboxylate utilizing Ti-Claisen Condensation
Ashida Y, et al.
Organic Syntheses, 93, 286-286 (2016)
4-Methoxycarbonyl-2-methyl-1,3-oxazole
White JD, et al
Organic Syntheses, 79, 244-244 (2002)
Katherine R Phillips et al.
Journal of the American Chemical Society, 135(2), 574-577 (2012-12-28)
Methyl formate is produced from the photo-oxidation of methanol on preoxidized TiO(2)(110). We demonstrate that two consecutive photo-oxidation steps lead to methyl formate using mass spectrometry and scanning tunneling microscopy. The first step in methanol oxidation is formation of methoxy
Methyl N-Phenyl Carbamate Synthesis from Aniline and Methyl Formate: Carbon Recycling to Chemical Products.
Yalfani MS, et al.
ChemSusChem, 8(3), 443-447 (2015)
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