67692
Iodomethane
≥99.0% (GC), purum
동의어(들):
Methyl iodide
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제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
CH3I
CAS 번호:
Molecular Weight:
141.94
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
200-819-5
MDL number:
Beilstein/REAXYS Number:
969135
Assay:
≥99.0% (GC)
제품 이름
Iodomethane, purum, ≥99.0% (GC)
vapor density
4.89 (vs air)
Quality Level
vapor pressure
24.09 psi ( 55 °C), 7.89 psi ( 20 °C)
grade
purum
assay
≥99.0% (GC)
contains
silver wool as stabilizer
impurities
≤0.5% CH2I2
refractive index
n20/D 1.530, n20/D 1.531 (lit.)
bp
41-43 °C
mp
−64 (lit.)
solubility
water: soluble 14 g/L at 20 °C
density
2.28 g/mL at 25 °C (lit.)
functional group
alkyl halide, iodo
SMILES string
CI
InChI
1S/CH3I/c1-2/h1H3
InChI key
INQOMBQAUSQDDS-UHFFFAOYSA-N
General description
Iodomethane (Methyl iodide) is a colorless liquid. It can be prepared by reacting dimethyl sulfate with concentrated KI. Reaction of iodine and phosphorous with methanol has been reported to afford iodomethane. It reacts with tris(triphenylphosphine)chlororhodium(I) to afford the octahedral complex of rhodium(III), [RhlCl(CH3)(PPh3)2(ICH3)]. Kinetics of its reaction with atomic chlorine in the gas phase has been investigated. The absolute rate constant of the reaction has been reported.
Application
Iodomethane (Methyl iodide) may be employed in the preparation of stable neutral solutions of hypoiodous acid and various methyl esters.
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signalword
Danger
target_organs
Respiratory system
저장 등급
3 - Flammable liquids
flash_point_f
89.8 °F - closed cup
flash_point_c
32.1 °C - closed cup
ppe
Faceshields, Gloves, Goggles
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Farabi Temel
Talanta, 211, 120725-120725 (2020-02-20)
This work designs the synthesis of a novel amino morpholine schiff base functionalized calix[4]arene cage (SCC), its deposition onto Quartz Crystal Microbalance (QCM) crystal surface, and usage for the selective detecting of formaldehyde (HCHO). The SCC modified QCM sensor has
Interaction of tris (triphenylphosphine) chlororhodium (I) with iodomethane, methylallyl, and allyl chloride.
Lawson DN, et al.
J. Chem. Soc. Sect. A, 1733-1736 (1966)
Efficient methylation of carboxylic acids with potassium hydroxide/methyl sulfoxide and iodomethane.
Avila-Zarraga JG and Martinez R.
Synthetic Communications, 31(14), 2177-2183 (2001)