215406
Ammonium iron(II) sulfate hexahydrate
ACS reagent, 99%
동의어(들):
Ammonium ferrous sulfate hexahydrate, Ammonium iron(II) sulfate, Mohr’s salt
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
(NH4)2Fe(SO4)2 · 6H2O
CAS 번호:
Molecular Weight:
392.14
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-151-8
MDL number:
Assay:
98.5-101.5%, 99%
Grade:
ACS reagent
Form:
powder or crystals
grade
ACS reagent
Quality Level
assay
98.5-101.5%, 99%
form
powder or crystals
reaction suitability
reagent type: catalyst
core: iron
impurities
≤0.01% insolubles, ≤0.05% Not NH4OH pptd.
pH
3-5 (20 °C, 50 g/L)
mp
100 °C (dec.) (lit.)
anion traces
phosphate (PO43-): ≤0.003%
cation traces
Ca: 0.005%, Cu: ≤0.003%, Fe3+: ≤0.01%, K: 0.002%, Mg: 0.002%, Mn: ≤0.01%, Na: 0.02%, Zn: ≤0.003%
SMILES string
N.N.O.O.O.O.O.O.[Fe++].OS([O-])(=O)=O.OS([O-])(=O)=O
InChI
1S/Fe.2H3N.2H2O4S.6H2O/c;;;2*1-5(2,3)4;;;;;;/h;2*1H3;2*(H2,1,2,3,4);6*1H2/q+2;;;;;;;;;;/p-2
InChI key
MQLVWQSVRZVNIP-UHFFFAOYSA-L
Application
Ammonium iron(II) sulfate hexahydrate can be used as a green catalyst in the:
- Newman-Kwart rearrangement to synthesize functionalized thiophenols.
- Oxidation of aromatic, aliphatic, and conjugated aldehydes to the corresponding carboxylic acids.
- Synthesis of biscoumarins via condensation reaction.
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저장 등급
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Konstantinos Grintzalis et al.
Free radical biology & medicine, 59, 27-35 (2012-10-09)
A simple and sensitive method is presented for the simultaneous quantification (spectrophotometric and spectrofluorimetric) of the main lipid and protein peroxidation products after their initial fractionation: free malondialdehyde (FrMDA), protein-bound malondialdehyde (PrMDA), total hydroperoxides (LOOH), and protein hydroperoxides (PrOOH). FrMDA
Metallization of biologically inspired silica nanotubes.
Jo W, et al.
Materials Science and Engineering, C, 32(8), 2426-2430 (2012)
Mixed ligand complexes of iron (II) and (III) with cyanide and aromatic di-imines.
Schilt AA.
Journal of the American Chemical Society, 82(12), 3000-3005 (1960)