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Merck

791776

Potassium carbonate

anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99%

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
K2CO3
CAS 번호:
Molecular Weight:
138.21
UNSPSC Code:
12352302
NACRES:
NA.21
PubChem Substance ID:
EC Number:
209-529-3
Beilstein/REAXYS Number:
4267587
MDL number:
Assay:
≥99%
Grade:
ACS reagent, anhydrous
Form:
powder
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Quality Level

grade

ACS reagent, anhydrous

product line

Redi-Dri

assay

≥99%

form

powder

quality

free-flowing

impurities

≤0.005% silica, ≤0.01% insolubles

pH

11-13 (25 °C, 138 g/L)

mp

891 °C (lit.)

anion traces

chloride (Cl-): ≤0.003%, phosphate (PO43-): ≤0.001%, sulfur compounds (as SO42-): ≤0.004%

cation traces

Ca: ≤0.005%, Fe: ≤5 ppm, Mg: ≤0.002%, Na: ≤0.02%, heavy metals (as Pb): ≤5 ppm

SMILES string

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

BWHMMNNQKKPAPP-UHFFFAOYSA-L

General description

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene. Addition of amino acids (glycine, sarcosine and proline) to K2CO3 (solvent) promotes the absorption of CO2.

Application

Potassium carbonate has been used in the preparation of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone, a disulfonated diamine monomer.

It may be used:
  • As a reagent in the synthesis of polysubstituted iodobenzene derivatives.
  • As a base for the synthesis of high molecular weight homopolymers and copolymers derived from various bisphenols.
  • As a base for the Suzuki coupling of aryl halides with aryl boronic acids.
  • In the Heck reaction of styrene and bromobenzene.

Features and Benefits

  • Increased efficiency – Eliminate time and effort of loosening hardened powders
  • Safety – Avoid risks of using tools of force to break up clumps
  • Economy – Faster preparation and solvation increase productivity and reduce costs
  • Assured quality – Excellent, expert-tested quality with no anti-caking agents
  • Flexible volumes – Available from research amounts to scale-up quantities

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC


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Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

저장 등급

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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문서

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.


Adam F Nugraha et al.
Polymers, 12(7) (2020-07-24)
Several methods to synthesize poly(phenylene) block copolymers through the nickel coupling reaction were attempted to reduce the use of expensive nickel catalysts in polymerization. The model reaction for poly(phenylene) having different types of dichlorobenzene derivative monomers illustrated the potential use
Yusuke Yagi et al.
Organic & biomolecular chemistry, 13(4), 1113-1121 (2014-11-26)
Fluorine-18 labeled radiotracers, such as [(18)F]fluorodeoxyglucose, can be used as practical diagnostic agents in positron emission tomography (PET). Furthermore, the properties of pharmaceuticals can be enhanced significantly by the introduction of fluorine groups into their original structures, and significant progress
Ellen Dirkx et al.
Journal of molecular and cellular cardiology, 76, 208-217 (2014-09-01)
In the insulin resistant heart, energy fuel selection shifts away from glucose utilization towards almost complete dependence on long-chain fatty acids (LCFA). This shift results in excessive cardiac lipid accumulation and eventually heart failure. Lipid-induced cardiomyopathy may be averted by